The column density distribution of trapped OH$^-$ ions in a 22-pole ion trap is measured for different trap parameters. The density is obtained from position-dependent photodetachment rate measurements. Overall, agreement is found with the effective potential of an ideal 22-pole. However, in addition we observe 10 distinct minima in the trapping potential, which indicate a breaking of the 22-fold symmetry. Numerical simulations show that a displacement of a subset of the radiofrequency electrodes can serve as an explanation for this symmetry breaking.
