Structural Features of Layered Iron Pnictide Oxides (Fe2As2)(Sr4M2O6)

التفاصيل البيبلوغرافية
العنوان: Structural Features of Layered Iron Pnictide Oxides (Fe2As2)(Sr4M2O6)
المؤلفون: Ogino, H., Sato, S., Matsumura, Y., Kawaguchi, N., Ushiyama, K., Katsura, Y., Horii, S., Kishio, K., Shimoyama, J.
سنة النشر: 2010
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Superconductivity
الوصف: Structural features of newly found perovskite-based iron pnictide oxide system have been systematically studied. Compared to REFePnO system, perovskite-based system tend to have lower Pn-Fe-Pn angle and higher pnictogen height owing to low electronegativity of alkaline earth metal and small repulsive force between pnictogen and oxygen atoms. As-Fe-As angles of (Fe2As2)(Sr4Cr2O6), (Fe2As2)(Sr4V2O6) and (Fe2Pn2)(Sr4MgTiO6) are close to ideal tetrahedron and those pnictogen heights of about 1.40 A are close to NdFeAsO with optimized carrier concentration. These structural features of this system may leads to realization of high Tc superconductivity.
Comment: 3pages, 2figures, 1table, proceedings of M2S 2009
نوع الوثيقة: Working Paper
DOI: 10.1016/j.physc.2009.10.099
URL الوصول: http://arxiv.org/abs/1006.2351
رقم الأكسشن: edsarx.1006.2351
قاعدة البيانات: arXiv