Surface Atom Motion to Move Iron Nanocrystals through Constrictions in Carbon Nanotubes under the Action of an Electric Current

التفاصيل البيبلوغرافية
العنوان: Surface Atom Motion to Move Iron Nanocrystals through Constrictions in Carbon Nanotubes under the Action of an Electric Current
المؤلفون: Coh, Sinisa, Gannett, Will, Zettl, A., Cohen, Marvin L., Louie, Steven G.
المصدر: Phys. Rev. Lett. 110, 185901 (2013)
سنة النشر: 2013
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Mesoscale and Nanoscale Physics, Condensed Matter - Materials Science
الوصف: Under the application of electrical currents, metal nanocrystals inside carbon nanotubes can be bodily transported. We examine experimentally and theoretically how an iron nanocrystal can pass through a constriction in the carbon nanotube with a smaller cross-sectional area than the nanocrystal itself. Remarkably, through in situ transmission electron imaging and diffraction, we find that, while passing through a constriction, the nanocrystal remains largely solid and crystalline and the carbon nanotube is unaffected. We account for this behavior by a pattern of iron atom motion and rearrangement on the surface of the nanocrystal. The nanocrystal motion can be described with a model whose parameters are nearly independent of the nanocrystal length, area, temperature, and electromigration force magnitude. We predict that metal nanocrystals can move through complex geometries and constrictions, with implications for both nanomechanics and tunable synthesis of metal nanoparticles.
Comment: 5 pages, 4 figures
نوع الوثيقة: Working Paper
DOI: 10.1103/PhysRevLett.110.185901
URL الوصول: http://arxiv.org/abs/1302.5709
رقم الأكسشن: edsarx.1302.5709
قاعدة البيانات: arXiv
الوصف
DOI:10.1103/PhysRevLett.110.185901