Electrocaloric effect and high energy storage efficiency in lead-free Ba$_{0.95}$Ca$_{0.05}$Ti$_{0.89}$Sn$_{0.11}$O$_3$ ceramic elaborated by sol-gel method

التفاصيل البيبلوغرافية
العنوان: Electrocaloric effect and high energy storage efficiency in lead-free Ba$_{0.95}$Ca$_{0.05}$Ti$_{0.89}$Sn$_{0.11}$O$_3$ ceramic elaborated by sol-gel method
المؤلفون: Hadouch, Youness, Moumen, Said Ben, Mezzourh, Hanane, Mezzane, Daoud, Amjoud, M'barek, Asbani, Bouchra, Razumnaya, Anna G., Gagou, Yaovi, Rožič, Brigita, Kutnjak, Zdravko, Marssi, Mimoun El
سنة النشر: 2022
المجموعة: Condensed Matter
مصطلحات موضوعية: Condensed Matter - Materials Science
الوصف: Structural, dielectric, ferroelectric, energy storage properties, and electrocaloric effect were studied in lead-free ceramic Ba$_{0.95}$Ca$_{0.05}$Ti$_{0.89}$Sn$_{0.11}$O$_3$ (BCTSn) elaborated by sol-gel method. Phase purity structure was confirmed from X-ray data using Rietveld refinement analysis which revealed the coexistence of tetragonal (P4mm) and orthorhombic (Amm2) symmetries at room temperature. Phase transitions were detected by dielectric and differential scanning calorimetry results. Energy storage properties were determined from P-E hysteresis, and the electrocaloric properties were calculated indirectly via the Maxwell approach. The large value of electrocaloric temperature change of $\Delta$T=0.807 K obtained at a relatively small field of 30 kV cm$^{-1}$ and high energy storage efficiency can make BCTSn ceramic a promising candidate for environmentally friendly refrigeration and energy storage applications.
نوع الوثيقة: Working Paper
URL الوصول: http://arxiv.org/abs/2209.10628
رقم الأكسشن: edsarx.2209.10628
قاعدة البيانات: arXiv