Let $R$ be a prime ring of characteristic different from $2$, $U$ be its Utumi quotient ring, $C$ be its extended centroid and $L$ be a non-central Lie ideal of $R$. Suppose $F$ and $G$ are two non-zero $b$-generalized skew derivations of $R$ associated with the same automorphism $\alpha$ such that $$puF(u) + F(u)uq = G(u^2),\ \text{with} \ p + q \notin C,~~ \text{for all $u \in L$. }$$ This paper aims to study the complete structure of the $\mathrm{b}$-generalized skew derivations $F$ and $G$.