After decades of research, superconductivity was finally found in nickel-based analogs of superconducting cuprates, with infinite-layer (IL) structure. These results are so far restricted to thin films in the case of IL-nickelates. Therefore, the nature of the interface with the substrate, and how it couples with the thin film properties is still an open question. Here, using scanning transmission electron microscopy (STEM)- electron energy loss spectroscopy (EELS) and four-dimensional (4D)-STEM, a novel chemically sharp p-type interface is observed in a series of superconducting IL-praseodymium nickelate samples, and a comparative study is carried out with the previously reported n-type interface obtained in other samples. Both interfaces have strong differences, with the p-type interface being highly polar. In combination with ab-initio calculations, we find that the influence of the interface on the electronic structure is local, and does not extend beyond 2-3 unit cells into the thin film. This decouples the direct influence of the interface in driving the superconductivity, and indicates that the IL-nickelate thin films do not have a universal interface model. Insights into the spatial hole-distribution in SC samples, provided by monochromated EELS and total reflection-hard x-ray photoemission spectroscopy, suggest that this particular distribution might be directly influencing superconductivity.
