تقرير
The surface termination of a Fe (III) spin crossover molecular salt
| العنوان: | The surface termination of a Fe (III) spin crossover molecular salt |
|---|---|
| المؤلفون: | Zaz, M. Zaid, Tamang, Binny, McElven, Kayleigh, Mishra, Esha, Viswan, Gauthami, Chin, Wai Kiat, Subedi, Arjun, Daiye, Alpha T. Ń, Lai, Rebecca, Dowben, Peter A. |
| سنة النشر: | 2024 |
| المجموعة: | Condensed Matter |
| مصطلحات موضوعية: | Condensed Matter - Materials Science |
| الوصف: | From a comparison of energy dispersive analyses of X-rays (EDAX), the known molecular stoichiometry and X-ray photoemission spectroscopy (XPS), it is evident that the Fe(III) spin crossover salt [Fe(qsal)2Ni(dmit)2] has a preferential surface termination with the Ni(dmit)2 moiety. This preferential surface termination leads to a significant surface to bulk core level shift for the Ni 2p X-ray photoemission core level, not seen in the corresponding Fe 2p core level spectra. Inverse photoemission spectroscopy (IPES), thus provides some indication of the density of states resulting from the dmit2 = 1,3-dithiol-2-thione-4,5-dithiolato ligand unoccupied molecular orbitals. Comment: 5 pages, 4 figures, submitted for publication in JPCM |
| نوع الوثيقة: | Working Paper |
| URL الوصول: | http://arxiv.org/abs/2408.07138 |
| رقم الأكسشن: | edsarx.2408.07138 |
| قاعدة البيانات: | arXiv |
| الوصف غير متاح. |