دورية أكاديمية
Emission of biogenic volatile organic compounds from warm and oligotrophic seawater in the Eastern Mediterranean
| العنوان: | Emission of biogenic volatile organic compounds from warm and oligotrophic seawater in the Eastern Mediterranean |
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| المؤلفون: | C. Dayan, E. Fredj, P. K. Misztal, M. Gabay, A. B. Guenther, E. Tas |
| المصدر: | Atmospheric Chemistry and Physics, Vol 20, Pp 12741-12759 (2020) |
| بيانات النشر: | Copernicus Publications, 2020. |
| سنة النشر: | 2020 |
| المجموعة: | LCC:Physics LCC:Chemistry |
| مصطلحات موضوعية: | Physics, QC1-999, Chemistry, QD1-999 |
| الوصف: | Biogenic volatile organic compounds (BVOCs) from terrestrial vegetation and marine organisms contribute to photochemical pollution and affect the radiation budget, cloud properties and precipitation via secondary organic aerosol formation. Their emission from both marine and terrestrial ecosystems is substantially affected by climate change in ways that are currently not well characterized. The Eastern Mediterranean Sea was identified as a climate change “hot spot”, making it a natural laboratory for investigating the impact of climate change on BVOC emissions from both terrestrial and marine vegetation. We quantified the mixing ratios of a suite of volatile organic compounds (VOCs), including isoprene, dimethyl sulfide (DMS), acetone, acetaldehyde and monoterpenes, at a mixed vegetation site ∼4 km from the southeastern tip of the Levantine Basin, where the sea surface temperature (SST) maximizes and ultra-oligotrophic conditions prevail. The measurements were performed between July and October 2015 using a proton transfer reaction time-of-flight mass spectrometer (PTR-ToF-MS). The analyses were supported by the Model of Emissions of Gases and Aerosols from Nature (MEGAN v2.1). For isoprene and DMS mixing ratios, we identified a dominant contribution from the seawater. Our analyses further suggest a major contribution, at least for monoterpenes, from the seawater. Our results indicate that the Levantine Basin greatly contributes to isoprene emissions, corresponding with mixing ratios of up to ∼9 ppbv several kilometers inland from the sea shore. This highlights the need to update air quality and climate models to account for the impact of SST on marine isoprene emission. The DMS mixing ratios were 1 to 2 orders of magnitude lower than those measured in 1995 in the same area, suggesting a dramatic decrease in emissions due to changes in the species composition induced by the rise in SST. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 1680-7316 1680-7324 |
| Relation: | https://acp.copernicus.org/articles/20/12741/2020/acp-20-12741-2020.pdf; https://doaj.org/toc/1680-7316; https://doaj.org/toc/1680-7324 |
| DOI: | 10.5194/acp-20-12741-2020 |
| URL الوصول: | https://doaj.org/article/3ce3840083564dbda46c4843d3a71df1 |
| رقم الأكسشن: | edsdoj.3ce3840083564dbda46c4843d3a71df1 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 16807316 16807324 |
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| DOI: | 10.5194/acp-20-12741-2020 |