Summary: Solar-driven production of fuels such as hydrogen, hydrocarbons, and ammonia using semiconducting photocatalysts has the potential to be a sustainable alternative to current chemical processes. In recent years, silicon (Si) nanostructures have been recognized as a promising photocatalyst for hydrogen generation and organic oxidation reactions owing to its abundance, biocompatibility, and cost. While bulk Si has been studied extensively, on the nanoscale, plenty of opportunities exist to understand and engineer optimally performing Si photocatalysts. This perspective will highlight key results on the use of Si nanostructures for photocatalytic H2 production, CO2 reduction via light and heat-driven chemical looping, and current challenges in utilizing it for fuel-forming reactions. A brief guide on how these challenges can be addressed in the future and other unexplored questions that remain in the field are also discussed.
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