دورية أكاديمية
Tuning the viscoelastic features required for 3D printing of PVC-acrylate copolymers obtained by single electron transfer-degenerative chain transfer living radical polymerization (SET-DTLRP)
العنوان: | Tuning the viscoelastic features required for 3D printing of PVC-acrylate copolymers obtained by single electron transfer-degenerative chain transfer living radical polymerization (SET-DTLRP) |
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المؤلفون: | M. I. Calafel, R. H. Aguirresarobe, N. Sadaba, M. Boix, J. I. Conde, B. Pascual, A. Santamaria |
المصدر: | eXPRESS Polymer Letters, Vol 12, Iss 9, Pp 824-835 (2018) |
بيانات النشر: | Budapest University of Technology, 2018. |
سنة النشر: | 2018 |
المجموعة: | LCC:Materials of engineering and construction. Mechanics of materials LCC:Chemical technology |
مصطلحات موضوعية: | Rheology, Processing technologies, 3D-Printing, Dynamic viscoelasticity, PVC-Acrylate copolymers, Materials of engineering and construction. Mechanics of materials, TA401-492, Chemical technology, TP1-1185 |
الوصف: | Random poly (vinyl chloride-co-butyl acrylate) and poly (vinyl chloride-co-2-ethylhexyl acrylate copolymers obtained by single electron transfer-degenerative chain transfer living radical polymerization (SET- DTLRP) are investigated as potential candidates for 3D Printing. The analysis of the rheological implications of 3D Printing process allows establishing the basic viscoelastic conditions that the samples should fulfil to be printable, avoiding the ‘trial and error’ procedure. The effect of temperature and acrylates concentration on the rheological properties and 3D printing feasibility is contemplated. Eventually, thermal degradation is also considered. It is demonstrated that the copolymers which contain butyl acrylate comonomer, instead of 2-ethylhexyl acrylate, give raise to the best results. Although the study is carried out with PVCacrylate copolymers and a 3D printing device that possesses set up characteristics, it shows a way to work out sound strategies with other polymers and 3D printing machines. |
نوع الوثيقة: | article |
وصف الملف: | electronic resource |
اللغة: | English |
تدمد: | 1788-618X |
Relation: | http://www.expresspolymlett.com/letolt.php?file=EPL-0009146&mi=cd; https://doaj.org/toc/1788-618X |
DOI: | 10.3144/expresspolymlett.2018.70 |
URL الوصول: | https://doaj.org/article/5dbb5b2925d245abb156758f68393c31 |
رقم الأكسشن: | edsdoj.5dbb5b2925d245abb156758f68393c31 |
قاعدة البيانات: | Directory of Open Access Journals |
تدمد: | 1788618X |
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DOI: | 10.3144/expresspolymlett.2018.70 |