دورية أكاديمية

Tuning the viscoelastic features required for 3D printing of PVC-acrylate copolymers obtained by single electron transfer-degenerative chain transfer living radical polymerization (SET-DTLRP)

التفاصيل البيبلوغرافية
العنوان: Tuning the viscoelastic features required for 3D printing of PVC-acrylate copolymers obtained by single electron transfer-degenerative chain transfer living radical polymerization (SET-DTLRP)
المؤلفون: M. I. Calafel, R. H. Aguirresarobe, N. Sadaba, M. Boix, J. I. Conde, B. Pascual, A. Santamaria
المصدر: eXPRESS Polymer Letters, Vol 12, Iss 9, Pp 824-835 (2018)
بيانات النشر: Budapest University of Technology, 2018.
سنة النشر: 2018
المجموعة: LCC:Materials of engineering and construction. Mechanics of materials
LCC:Chemical technology
مصطلحات موضوعية: Rheology, Processing technologies, 3D-Printing, Dynamic viscoelasticity, PVC-Acrylate copolymers, Materials of engineering and construction. Mechanics of materials, TA401-492, Chemical technology, TP1-1185
الوصف: Random poly (vinyl chloride-co-butyl acrylate) and poly (vinyl chloride-co-2-ethylhexyl acrylate copolymers obtained by single electron transfer-degenerative chain transfer living radical polymerization (SET- DTLRP) are investigated as potential candidates for 3D Printing. The analysis of the rheological implications of 3D Printing process allows establishing the basic viscoelastic conditions that the samples should fulfil to be printable, avoiding the ‘trial and error’ procedure. The effect of temperature and acrylates concentration on the rheological properties and 3D printing feasibility is contemplated. Eventually, thermal degradation is also considered. It is demonstrated that the copolymers which contain butyl acrylate comonomer, instead of 2-ethylhexyl acrylate, give raise to the best results. Although the study is carried out with PVCacrylate copolymers and a 3D printing device that possesses set up characteristics, it shows a way to work out sound strategies with other polymers and 3D printing machines.
نوع الوثيقة: article
وصف الملف: electronic resource
اللغة: English
تدمد: 1788-618X
Relation: http://www.expresspolymlett.com/letolt.php?file=EPL-0009146&mi=cd; https://doaj.org/toc/1788-618X
DOI: 10.3144/expresspolymlett.2018.70
URL الوصول: https://doaj.org/article/5dbb5b2925d245abb156758f68393c31
رقم الأكسشن: edsdoj.5dbb5b2925d245abb156758f68393c31
قاعدة البيانات: Directory of Open Access Journals
الوصف
تدمد:1788618X
DOI:10.3144/expresspolymlett.2018.70