دورية أكاديمية
Structural, Magnetic and Luminescent Properties of Lanthanide Complexes with N-Salicylideneglycine
| العنوان: | Structural, Magnetic and Luminescent Properties of Lanthanide Complexes with N-Salicylideneglycine |
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| المؤلفون: | Ján Vančo, Zdeněk Trávníček, Ondřej Kozák, Roman Boča |
| المصدر: | International Journal of Molecular Sciences, Vol 16, Iss 5, Pp 9520-9539 (2015) |
| بيانات النشر: | MDPI AG, 2015. |
| سنة النشر: | 2015 |
| المجموعة: | LCC:Biology (General) LCC:Chemistry |
| مصطلحات موضوعية: | lanthanide, Schiff base, salicylideneglycine, magnetic properties, luminescent properties, X-ray structure, Biology (General), QH301-705.5, Chemistry, QD1-999 |
| الوصف: | A series of anionic heavy lanthanide complexes, involving the N-salicylideneglycinato(2-) Schiff base ligand (salgly) and having the general formula K[Ln(salgly)2(H2O)2]∙H2O (1–6), where Ln stands for Gd, Tb, Dy, Ho, Er and Tm, was prepared using the one-pot template synthesis. The complexes were thoroughly characterized by elemental and Thermogravimetric/Differential Thermal Analyses (TG/DTA), Fourier Transform Infrared Spectroscopy (FT-IR), and photoluminescence spectroscopies, electrospray-ionization mass spectrometry, and their magnetic properties were studied by temperature-dependent dc magnetic measurements using the superconducting quantum interference device (SQUID). The X-ray structure of the terbium(III) complex (2), representing the unique structure between the lanthanide complexes of N-salicylideneamino acids, was determined. The results of spectral and structural studies revealed the isostructural nature of the prepared complexes, in which the lanthanide ion is octacoordinated by two O,N,O-donor salgly ligands and two aqua ligands. The analysis of magnetic data confirmed that the complexes behave as paramagnets obeying the Curie law. The results of photoluminescence spectral studies of the complexes showed the different origin in their luminescent properties between the solid state and solution. An antenna effect of the Schiff base ligand was observed in a powder form of the complex only, while it acts as a fluorophore in a solution. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 1422-0067 |
| Relation: | http://www.mdpi.com/1422-0067/16/5/9520; https://doaj.org/toc/1422-0067 |
| DOI: | 10.3390/ijms16059520 |
| URL الوصول: | https://doaj.org/article/d6481eea137f4e9482110c8dde27b4b0 |
| رقم الأكسشن: | edsdoj.6481eea137f4e9482110c8dde27b4b0 |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 14220067 |
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| DOI: | 10.3390/ijms16059520 |