دورية أكاديمية
Dimetallic praseodymium-cobalt carbon nanotubes as highly efficient electrocatalyst for oxygen reduction reaction
العنوان: | Dimetallic praseodymium-cobalt carbon nanotubes as highly efficient electrocatalyst for oxygen reduction reaction |
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المؤلفون: | Huazhong Liang, Yu Dong, Qin Ding, Xiaoyu Li, Miao Yu, Peihe Li, Limei Duan, Yin Wang |
المصدر: | Carbon Trends, Vol 15, Iss , Pp 100350- (2024) |
بيانات النشر: | Elsevier, 2024. |
سنة النشر: | 2024 |
المجموعة: | LCC:Chemistry |
مصطلحات موضوعية: | Praseodymium, Cobalt, Bimetallic, Oxygen reduction reaction, Metal-air batteries, Chemistry, QD1-999 |
الوصف: | In this study, six bimetallic rare earth (RE = La, Ce, Pr, Nd, Sm, Eu) cobalt nitrogen doped carbon nanotubes (RECo-NCNTs) were synthesized with g-C3N4 derivative method. These RECo-NCNTs were characterized by SEM, BET, XPS, XRD and Raman. In addition, their catalytic performances for oxygen reduction reaction (ORR) had also been tested. The introduction of rare earths did not destroy the structure of nanotubes but apparently change their ORR performances. The PrCo-NCNTs showed the significant improvement in catalytic ability for ORR (onset potential of 0.95 V and half-wave potential of 0.79 V), which is very close to that of commercial 20 % Pt/C. Moreover, PrCo-NCNTs exhibits an excellent catalytic stability (no activity decay after 10000st cycles) and an outstanding methanol toxic tolerance. Assembled in metal–air batteries (Zn-air, Al-air and Mg-air), the PrCo-NCNTs electrode also presents high power densities and discharge voltages. |
نوع الوثيقة: | article |
وصف الملف: | electronic resource |
اللغة: | English |
تدمد: | 2667-0569 |
Relation: | http://www.sciencedirect.com/science/article/pii/S2667056924000312; https://doaj.org/toc/2667-0569 |
DOI: | 10.1016/j.cartre.2024.100350 |
URL الوصول: | https://doaj.org/article/ab3312c48c214bd3abcb8270476b00cd |
رقم الأكسشن: | edsdoj.b3312c48c214bd3abcb8270476b00cd |
قاعدة البيانات: | Directory of Open Access Journals |
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