دورية أكاديمية
Hydroxyapatite Growth on Activated Carbon Surface for Methylene Blue Adsorption: Effect of Oxidation Time and CaSiO3 Addition on Hydrothermal Incubation
العنوان: | Hydroxyapatite Growth on Activated Carbon Surface for Methylene Blue Adsorption: Effect of Oxidation Time and CaSiO3 Addition on Hydrothermal Incubation |
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المؤلفون: | Anastasio Moreno-Santos, Jorge Carlos Rios-Hurtado, Sergio Enrique Flores-Villaseñor, Alma Graciela Esmeralda-Gomez, Juanita Yazmin Guevara-Chavez, Fatima Pamela Lara-Castillo, Griselda Berenice Escalante-Ibarra |
المصدر: | Applied Sciences, Vol 13, Iss 1, p 77 (2022) |
بيانات النشر: | MDPI AG, 2022. |
سنة النشر: | 2022 |
المجموعة: | LCC:Technology LCC:Engineering (General). Civil engineering (General) LCC:Biology (General) LCC:Physics LCC:Chemistry |
مصطلحات موضوعية: | activated carbon, CaSiO3, oxidation, hydroxyapatite, methylene blue, adsorption, Technology, Engineering (General). Civil engineering (General), TA1-2040, Biology (General), QH301-705.5, Physics, QC1-999, Chemistry, QD1-999 |
الوصف: | Many adsorbent materials are now commercially available; however, studies have focused on modifying them to enhance their properties. In this study, an activated carbon (AC) and hydroxyapatite (HAp) composite was synthesized by the immersion of ACs in a simulated body fluid solution, varying the AC oxidation degree along with the addition of CaSiO3. The resulting composites were characterized by ash %, X-ray fluorescence (XRF), Fourier-transformed infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and point of zero charge (PZC). The characterization results indicated that the addition of CaSiO3 and the oxygenated functional groups in the AC surface are key factors for HAp growth. The composites were tested on methylene blue (MB) adsorption as a potential application for the synthesized materials. Adsorption isotherms were modeled with Langmuir and Freundlich isotherms, and the composites were fitted to a Langmuir model with the highest qmax value of 9.82. The kinetic results indicated that for the pseudo-second-order model, the composites fitted, with a contact time of 180 min to remove a 95.61% average of the MB. The results indicate that composite materials can be an efficient adsorbent for the removal of MB from aqueous solutions at low concentrations since the material with the highest amount of HAp growth removed 99.8% of the MB in 180 min. |
نوع الوثيقة: | article |
وصف الملف: | electronic resource |
اللغة: | English |
تدمد: | 13010077 2076-3417 |
Relation: | https://www.mdpi.com/2076-3417/13/1/77; https://doaj.org/toc/2076-3417 |
DOI: | 10.3390/app13010077 |
URL الوصول: | https://doaj.org/article/df4ae2bb38db48409749be867c3fd66b |
رقم الأكسشن: | edsdoj.f4ae2bb38db48409749be867c3fd66b |
قاعدة البيانات: | Directory of Open Access Journals |
تدمد: | 13010077 20763417 |
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DOI: | 10.3390/app13010077 |