دورية أكاديمية
Ortho-ester-substituted diaryliodonium salts enabled regioselective arylocyclization of naphthols toward 3,4-benzocoumarins
| العنوان: | Ortho-ester-substituted diaryliodonium salts enabled regioselective arylocyclization of naphthols toward 3,4-benzocoumarins |
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| المؤلفون: | Ke Jiang, Cheng Pan, Limin Wang, Hao-Yang Wang, Jianwei Han |
| المصدر: | Beilstein Journal of Organic Chemistry, Vol 20, Iss 1, Pp 841-851 (2024) |
| بيانات النشر: | Beilstein-Institut, 2024. |
| سنة النشر: | 2024 |
| المجموعة: | LCC:Science LCC:Organic chemistry |
| مصطلحات موضوعية: | annulation, arylocyclization, 3,4-benzocoumarin, diaryliodonium salts, naphthol, Science, Organic chemistry, QD241-441 |
| الوصف: | Cyclic annulation involving diaryliodonium salts is an efficient tool for the construction of two or more chemical bonds in a one-pot process. Ortho-functionalized diaryliodonium salts have showcased distinct reactivity in the exploration of benzocyclization or arylocyclization. With this strategy of ortho-ester-substituted diaryliodonium salts, herein, we utilized a copper catalyst to activate the C–I bond of diaryliodonium salts in the generation of aryl radicals, thus resulting in an annulation reaction with naphthols and substituted phenols. This approach yielded a diverse array of 3,4-benzocoumarin derivatives bearing various substituents. |
| نوع الوثيقة: | article |
| وصف الملف: | electronic resource |
| اللغة: | English |
| تدمد: | 1860-5397 |
| Relation: | https://doaj.org/toc/1860-5397 |
| DOI: | 10.3762/bjoc.20.76 |
| URL الوصول: | https://doaj.org/article/ff79335e63c24be7ae193788d0f58a9b |
| رقم الأكسشن: | edsdoj.ff79335e63c24be7ae193788d0f58a9b |
| قاعدة البيانات: | Directory of Open Access Journals |
Full Text Finder | تدمد: | 18605397 |
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| DOI: | 10.3762/bjoc.20.76 |