دورية أكاديمية

Determination of Copper, Iron, Nickel and Zinc in fuel kerosene by FAAS after adsorption and pre-concentration on 2-aminothiazole-modified silica gel

التفاصيل البيبلوغرافية
العنوان: Determination of Copper, Iron, Nickel and Zinc in fuel kerosene by FAAS after adsorption and pre-concentration on 2-aminothiazole-modified silica gel
المؤلفون: Roldan, P. S., Alcântara, I. L., Rocha, J. C., Padilha, C. C. F., Padilha, P. M.
المصدر: Eclética Química. January 2004 29(2)
بيانات النشر: Fundação Editora da Universidade Estadual Paulista Júlio de Mesquita Filho - UNESP, 2004.
سنة النشر: 2004
مصطلحات موضوعية: preconcentration, modified silica gel, metal ions, fuel kerosene, FAAS determination
الوصف: Silica gel chemically modified with 2-Aminotiazole groups, abbreviated as SiAT, was used for preconcentration of copper, zinc, nickel and iron from kerosene, normally used as a engine fuel for airplanes. Surface characteristics and surface area of the silica gel were obtained before and after chemical modification using FT-IR, Kjeldhal and surface area analysis (B.E.T.). The retention and recovery of the analyte elements were studied by applying batch and column techniques. The experimental parameters, such as shaking time in batch technique, flow rate and concentration of the eluent (HCl- 0.25-2.00 mol L-1) and the amount of silica, on retention and elution, have been investigated. Detection limits of the method for copper, iron, nickel and zinc are 0.77, 2.92, 1.73 and 0.097 mg L-1, respectively. The sorption-desorption of the studied metal ions made possible the development of a preconcentration method for metal ions at trace level in kerosene using flame AAS for their quantification.
نوع الوثيقة: article
وصف الملف: text/html
اللغة: English
تدمد: 0100-4670
DOI: 10.1590/S0100-46702004000200005
URL الوصول: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702004000200005
حقوق: info:eu-repo/semantics/openAccess
رقم الأكسشن: edssci.S0100.46702004000200005
قاعدة البيانات: SciELO
الوصف
تدمد:01004670
DOI:10.1590/S0100-46702004000200005