دورية أكاديمية

A Small All-in-One Photon-Counting Device for Measuring Luminescence Decays to Determine the Lifetimes of Photoexcited Materials

التفاصيل البيبلوغرافية
العنوان: A Small All-in-One Photon-Counting Device for Measuring Luminescence Decays to Determine the Lifetimes of Photoexcited Materials
اللغة: English
المؤلفون: Matsubara, Yasuo (ORCID 0000-0001-9791-7197), Ito, Akitaka (ORCID 0000-0002-0893-5535)
المصدر: Journal of Chemical Education. Jan 2020 97(1):300-304.
الإتاحة: Division of Chemical Education, Inc. and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
Peer Reviewed: Y
Page Count: 5
تاريخ النشر: 2020
نوع الوثيقة: Journal Articles
Reports - Descriptive
Education Level: Higher Education
Postsecondary Education
Descriptors: Undergraduate Students, College Science, Lighting, Chemistry, Hands on Science, Spectroscopy, Measurement, Science Laboratories
DOI: 10.1021/acs.jchemed.9b00836
تدمد: 0021-9584
مستخلص: The lifetime of the excited state of a material is essential for characterizing its photophysical and photochemical processes and substantially affects the quantum efficiencies of its luminescence (fluorescence or phosphorescence) and photo(catalytic) reactions. However, undergraduate students are much more likely to do steady-state, rather than time-resolved, spectroscopy in a laboratory class. In this report, a small hand-held photon-counting device is proposed for this measurement within a time scale from about 100 ns to 10 s. Measurements of emission decays from excited chromium(III) in ruby as a photophysical example and ruthenium(II) tris(bipyridine), [Ru(bpy)[subscript 3]][superscript 2+], as a photochemical example are demonstrated using the device.
Abstractor: As Provided
Entry Date: 2020
رقم الأكسشن: EJ1240883
قاعدة البيانات: ERIC
الوصف
تدمد:0021-9584
DOI:10.1021/acs.jchemed.9b00836