دورية أكاديمية
Structure and catalytic function of Re-oxo species grafted onto H-MFI zeolite by sublimation of Re2O7.
العنوان: | Structure and catalytic function of Re-oxo species grafted onto H-MFI zeolite by sublimation of Re2O7. |
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المؤلفون: | Lacheen HS; Department of Chemical Engineering, University of California at Berkeley, California 94720, USA., Cordeiro PJ, Iglesia E |
المصدر: | Journal of the American Chemical Society [J Am Chem Soc] 2006 Nov 29; Vol. 128 (47), pp. 15082-3. |
نوع المنشور: | Journal Article |
اللغة: | English |
بيانات الدورية: | Publisher: American Chemical Society Country of Publication: United States NLM ID: 7503056 Publication Model: Print Cited Medium: Print ISSN: 0002-7863 (Print) Linking ISSN: 00027863 NLM ISO Abbreviation: J Am Chem Soc Subsets: PubMed not MEDLINE |
أسماء مطبوعة: | Publication: Washington, DC : American Chemical Society Original Publication: Easton, Pa. [etc.] |
مستخلص: | Isolated Re-oxo species within spatially constrained MFI zeolite channels were synthesized via exchange with Re2O7 vapor and shown to exist as isolated Re-oxo monomers. Turnover rates and Re-oxo structures did not depend on Re content. These materials were thermally stable and catalyzed alcohol oxidation reactions at unprecedented rates and near ambient temperatures. |
تواريخ الأحداث: | Date Created: 20061123 Date Completed: 20070104 Latest Revision: 20080117 |
رمز التحديث: | 20221213 |
DOI: | 10.1021/ja065832x |
PMID: | 17117847 |
قاعدة البيانات: | MEDLINE |
تدمد: | 0002-7863 |
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DOI: | 10.1021/ja065832x |