دورية أكاديمية
Ligand-assisted preparation of palladium supported nanoparticles: a step toward size control.
العنوان: | Ligand-assisted preparation of palladium supported nanoparticles: a step toward size control. |
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المؤلفون: | Rossi LM; Instituto de Química, Universidade de São Paulo, Brazil. lrossi@iq.usp.br, Nangoi IM, Costa NJ |
المصدر: | Inorganic chemistry [Inorg Chem] 2009 Jun 01; Vol. 48 (11), pp. 4640-2. |
نوع المنشور: | Journal Article |
اللغة: | English |
بيانات الدورية: | Publisher: American Chemical Society Country of Publication: United States NLM ID: 0366543 Publication Model: Print Cited Medium: Internet ISSN: 1520-510X (Electronic) Linking ISSN: 00201669 NLM ISO Abbreviation: Inorg Chem Subsets: MEDLINE |
أسماء مطبوعة: | Original Publication: [Easton, Pa.] American Chemical Society. |
مواضيع طبية MeSH: | Amines/*chemistry , Nanoparticles/*chemistry , Palladium/*chemistry, Catalysis ; Hydrogen/chemistry ; Ligands ; Particle Size ; Silicon Dioxide/chemistry ; Surface Properties |
مستخلص: | Supported nanoparticles (SNPs) with narrow size distribution were prepared by H(2) reduction of Pd(2+) previously bound to ligand-modified silica surfaces. Interestingly, the size of the Pd(0) SNPs was tuned by the ligand grafted on the support surface. Amino- and ethylenediamino-functionalized supports formed Pd(0) SNPs of ca. 6 and 1 nm, respectively. The catalytic properties of both Pd(0) SNPs were investigated. |
المشرفين على المادة: | 0 (Amines) 0 (Ligands) 5TWQ1V240M (Palladium) 7631-86-9 (Silicon Dioxide) 7YNJ3PO35Z (Hydrogen) |
تواريخ الأحداث: | Date Created: 20090430 Date Completed: 20090723 Latest Revision: 20131121 |
رمز التحديث: | 20240628 |
DOI: | 10.1021/ic900440p |
PMID: | 19400564 |
قاعدة البيانات: | MEDLINE |
تدمد: | 1520-510X |
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DOI: | 10.1021/ic900440p |