دورية أكاديمية

Ligand-assisted preparation of palladium supported nanoparticles: a step toward size control.

التفاصيل البيبلوغرافية
العنوان: Ligand-assisted preparation of palladium supported nanoparticles: a step toward size control.
المؤلفون: Rossi LM; Instituto de Química, Universidade de São Paulo, Brazil. lrossi@iq.usp.br, Nangoi IM, Costa NJ
المصدر: Inorganic chemistry [Inorg Chem] 2009 Jun 01; Vol. 48 (11), pp. 4640-2.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: American Chemical Society Country of Publication: United States NLM ID: 0366543 Publication Model: Print Cited Medium: Internet ISSN: 1520-510X (Electronic) Linking ISSN: 00201669 NLM ISO Abbreviation: Inorg Chem Subsets: MEDLINE
أسماء مطبوعة: Original Publication: [Easton, Pa.] American Chemical Society.
مواضيع طبية MeSH: Amines/*chemistry , Nanoparticles/*chemistry , Palladium/*chemistry, Catalysis ; Hydrogen/chemistry ; Ligands ; Particle Size ; Silicon Dioxide/chemistry ; Surface Properties
مستخلص: Supported nanoparticles (SNPs) with narrow size distribution were prepared by H(2) reduction of Pd(2+) previously bound to ligand-modified silica surfaces. Interestingly, the size of the Pd(0) SNPs was tuned by the ligand grafted on the support surface. Amino- and ethylenediamino-functionalized supports formed Pd(0) SNPs of ca. 6 and 1 nm, respectively. The catalytic properties of both Pd(0) SNPs were investigated.
المشرفين على المادة: 0 (Amines)
0 (Ligands)
5TWQ1V240M (Palladium)
7631-86-9 (Silicon Dioxide)
7YNJ3PO35Z (Hydrogen)
تواريخ الأحداث: Date Created: 20090430 Date Completed: 20090723 Latest Revision: 20131121
رمز التحديث: 20240628
DOI: 10.1021/ic900440p
PMID: 19400564
قاعدة البيانات: MEDLINE
الوصف
تدمد:1520-510X
DOI:10.1021/ic900440p