دورية أكاديمية
Transition-metal-free catalytic synthesis of 1,5-diaryl-1,2,3-triazoles.
العنوان: | Transition-metal-free catalytic synthesis of 1,5-diaryl-1,2,3-triazoles. |
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المؤلفون: | Kwok SW; The Scripps Research Institute, La Jolla, California 92037, USA., Fotsing JR, Fraser RJ, Rodionov VO, Fokin VV |
المصدر: | Organic letters [Org Lett] 2010 Oct 01; Vol. 12 (19), pp. 4217-9. |
نوع المنشور: | Journal Article; Research Support, N.I.H., Extramural; Research Support, Non-U.S. Gov't |
اللغة: | English |
بيانات الدورية: | Publisher: American Chemical Society Country of Publication: United States NLM ID: 100890393 Publication Model: Print Cited Medium: Internet ISSN: 1523-7052 (Electronic) Linking ISSN: 15237052 NLM ISO Abbreviation: Org Lett Subsets: MEDLINE |
أسماء مطبوعة: | Original Publication: Washington, DC : American Chemical Society, c1999- |
مواضيع طبية MeSH: | Triazoles/*chemical synthesis, Catalysis ; Hydroxides/chemistry ; Molecular Structure ; Transition Elements/chemistry |
مستخلص: | 1,5-Diarylsubstituted 1,2,3-triazoles are formed in high yield from aryl azides and terminal alkynes in DMSO in the presence of catalytic tetraalkylammonium hydroxide. The reaction is experimentally simple, does not require a transition-metal catalyst, and is not sensitive to atmospheric oxygen and moisture. |
References: | J Org Chem. 2002 May 3;67(9):3057-64. (PMID: 11975567) Org Lett. 2005 Apr 14;7(8):1469-72. (PMID: 15816729) Chem Soc Rev. 2007 Aug;36(8):1369-80. (PMID: 17619693) J Am Chem Soc. 2008 Jul 16;130(28):8923-30. (PMID: 18570425) Org Lett. 2004 Apr 15;6(8):1237-40. (PMID: 15070306) J Org Chem. 2003 May 2;68(9):3702-5. (PMID: 12713383) J Am Chem Soc. 2005 Nov 23;127(46):15998-9. (PMID: 16287266) Org Lett. 2007 Dec 20;9(26):5337-9. (PMID: 18052070) Chem Soc Rev. 2007 Aug;36(8):1249-62. (PMID: 17619685) Angew Chem Int Ed Engl. 2002 Jul 15;41(14):2596-9. (PMID: 12203546) |
معلومات مُعتمدة: | R01 GM087620 United States GM NIGMS NIH HHS; GM087620 United States GM NIGMS NIH HHS |
المشرفين على المادة: | 0 (Hydroxides) 0 (Transition Elements) 0 (Triazoles) |
تواريخ الأحداث: | Date Created: 20100910 Date Completed: 20110106 Latest Revision: 20211020 |
رمز التحديث: | 20240628 |
مُعرف محوري في PubMed: | PMC2946857 |
DOI: | 10.1021/ol101568d |
PMID: | 20825167 |
قاعدة البيانات: | MEDLINE |
تدمد: | 1523-7052 |
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DOI: | 10.1021/ol101568d |