دورية أكاديمية
[Ln(BH4)2(THF)2] (Ln = Eu, Yb)--a highly luminescent material. Synthesis, properties, reactivity, and NMR studies.
| العنوان: | [Ln(BH4)2(THF)2] (Ln = Eu, Yb)--a highly luminescent material. Synthesis, properties, reactivity, and NMR studies. |
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| المؤلفون: | Marks S; Institut für Anorganische Chemie, Karlsruher Institut für Technologie, Engesserstraße 15, 76131 Karlsruhe, Germany., Heck JG, Habicht MH, Oña-Burgos P, Feldmann C, Roesky PW |
| المصدر: | Journal of the American Chemical Society [J Am Chem Soc] 2012 Oct 17; Vol. 134 (41), pp. 16983-6. Date of Electronic Publication: 2012 Oct 04. |
| نوع المنشور: | Journal Article |
| اللغة: | English |
| بيانات الدورية: | Publisher: American Chemical Society Country of Publication: United States NLM ID: 7503056 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1520-5126 (Electronic) Linking ISSN: 00027863 NLM ISO Abbreviation: J Am Chem Soc Subsets: PubMed not MEDLINE |
| أسماء مطبوعة: | Publication: Washington, DC : American Chemical Society Original Publication: Easton, Pa. [etc.] |
| مستخلص: | The divalent lanthanide borohydrides [Ln(BH(4))(2)(THF)(2)] (Ln = Eu, Yb) have been prepared in a straightforward approach. The europium compound shows blue luminescence in the solid state, having a quantum yield of 75%. Nonradiative deactivation of C-H and B-H oscillator groups could be excluded in the perdeuterated complex [Eu(BD(4))(2)(d(8)-THF)(2)], which showed a quantum yield of 93%. The monocationic species [Ln(BH(4))(THF)(5)][BPh(4)] and the bis(phosphinimino)methanides [{(Me(3)SiNPPh(2))(2)CH}Ln(BH(4))(THF)(2)] have been prepared from [Ln(BH(4))(2)(THF)(2)]. They show significantly lower or no luminescence. Using the diamagnetic compound [{(Me(3)SiNPPh(2))(2)CH}Yb(BH(4))(THF)(2)], we performed a 2D (31)P/(171)Yb HMQC experiment. |
| تواريخ الأحداث: | Date Created: 20121006 Date Completed: 20130306 Latest Revision: 20121017 |
| رمز التحديث: | 20221213 |
| DOI: | 10.1021/ja308077t |
| PMID: | 23035876 |
| قاعدة البيانات: | MEDLINE |
Find this issue from the American Chemical Society | تدمد: | 1520-5126 |
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| DOI: | 10.1021/ja308077t |