دورية أكاديمية
Room-temperature photoinduced direct C-H-arylation via base-promoted homolytic aromatic substitution.
| العنوان: | Room-temperature photoinduced direct C-H-arylation via base-promoted homolytic aromatic substitution. |
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| المؤلفون: | Budén ME; INFIQC, Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, X5000HUA Córdoba, Argentina., Guastavino JF, Rossi RA |
| المصدر: | Organic letters [Org Lett] 2013 Mar 15; Vol. 15 (6), pp. 1174-7. Date of Electronic Publication: 2013 Mar 06. |
| نوع المنشور: | Journal Article; Research Support, Non-U.S. Gov't |
| اللغة: | English |
| بيانات الدورية: | Publisher: American Chemical Society Country of Publication: United States NLM ID: 100890393 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1523-7052 (Electronic) Linking ISSN: 15237052 NLM ISO Abbreviation: Org Lett Subsets: MEDLINE |
| أسماء مطبوعة: | Original Publication: Washington, DC : American Chemical Society, c1999- |
| مواضيع طبية MeSH: | Benzene Derivatives/*chemical synthesis , Thiophenes/*chemistry, Benzene Derivatives/chemistry ; Catalysis ; Combinatorial Chemistry Techniques ; Molecular Structure ; Photochemical Processes ; Temperature |
| مستخلص: | Conceptually different approach toward biaryl syntheses by photoinduced direct C-H arylation of benzene and thiophene in the presence of t-BuOK is reported. The reaction proceeds through photo- and base-promoted homolytic aromatic substitution. The o-, m- and p- substituted ArI, as well as the electron-donating and electron-withdrawing nature of the substituents were found be good to excellent substrates. Heteroaryl, ArBr, ArCl and double C-H arylation were successfully achieved. |
| المشرفين على المادة: | 0 (Benzene Derivatives) 0 (Thiophenes) |
| تواريخ الأحداث: | Date Created: 20130308 Date Completed: 20130724 Latest Revision: 20130315 |
| رمز التحديث: | 20221213 |
| DOI: | 10.1021/ol3034687 |
| PMID: | 23463911 |
| قاعدة البيانات: | MEDLINE |
Find this issue from the American Chemical Society | تدمد: | 1523-7052 |
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| DOI: | 10.1021/ol3034687 |