دورية أكاديمية
Crystal structure of bis-(1,3-bis-{[(1H-pyrrol-2-yl)methyl-idene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate.
| العنوان: | Crystal structure of bis-(1,3-bis-{[(1H-pyrrol-2-yl)methyl-idene]amino-κN}propan-2-olato-κO)manganese(III) nitrate methanol monosolvate. |
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| المؤلفون: | Ahn SH; Department of Chemistry, Kyungpook National University, Daegu 702-701, Republic of Korea., Shin JW; Beamline Department, Pohang Accelerator Laboratory/POSTECH 80, Pohang 790-784, South Korea., Moon D; Beamline Department, Pohang Accelerator Laboratory/POSTECH 80, Pohang 790-784, South Korea. |
| المصدر: | Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2014 Sep 17; Vol. 70 (Pt 10), pp. 210-2. Date of Electronic Publication: 2014 Sep 17 (Print Publication: 2014). |
| نوع المنشور: | Journal Article |
| اللغة: | English |
| بيانات الدورية: | Publisher: Wiley-Blackwell Country of Publication: United States NLM ID: 101089178 Publication Model: eCollection Cited Medium: Print ISSN: 1600-5368 (Print) Linking ISSN: 16005368 NLM ISO Abbreviation: Acta Crystallogr Sect E Struct Rep Online Subsets: PubMed not MEDLINE |
| أسماء مطبوعة: | Publication: <2008- > : Malden, MA : Wiley-Blackwell Original Publication: [Chester, England] : International Union of Crystallography, [2001]- |
| مستخلص: | The asymmetric unit of the title compound, [Mn(C13H15N4O)2]NO3·CH3OH, contains two independent complex cations, in each of which the Mn(III) ion is located on an inversion centre. The Mn(III) ion is coordinated by four N and two O atoms from two 1,3-bis-{[(1H-pyrrol-2-yl)methyl-idene]amino}-propan-2-olate ligands, resulting in a distorted octa-hedral geometry. The average Mn-ligand bond lengths in the two complex mol-ecules are 2.074 and 2.079 Å. In the crystal, inter-molecular N-H⋯O hydrogen bonds between the pyrrole group of the ligand and the non-coordinating nitrate ion give rise to a chain structure along [10-1]. The methanol solvent mol-ecule and the nitrate ion are connected by an O-H⋯O hydrogen bond. |
| References: | Chem Soc Rev. 2013 Feb 21;42(4):1784-95. (PMID: 22968285) Dalton Trans. 2012 May 28;41(20):6215-24. (PMID: 22488246) Acta Crystallogr B. 2002 Jun;58(Pt 3 Pt 1):380-8. (PMID: 12037359) Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. (PMID: 18156677) Inorg Chem. 2009 Dec 7;48(23):11176-86. (PMID: 19863089) |
| فهرسة مساهمة: | Keywords: Jahn–Teller distortion; crystal structure; hydrogen bonding; manganese(III) complex; propan-2-olate ligand; synchrotron study |
| تواريخ الأحداث: | Date Created: 20141209 Date Completed: 20141208 Latest Revision: 20200930 |
| رمز التحديث: | 20231215 |
| مُعرف محوري في PubMed: | PMC4257179 |
| DOI: | 10.1107/S1600536814020406 |
| PMID: | 25484654 |
| قاعدة البيانات: | MEDLINE |
Full Text Finder | تدمد: | 1600-5368 |
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| DOI: | 10.1107/S1600536814020406 |