التفاصيل البيبلوغرافية
| العنوان: |
First iron and cobalt(II) hexabromoclathrochelates: structural, magnetic, redox, and electrocatalytic behavior. |
| المؤلفون: |
Dolganov AV; Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 119991 Moscow, Russia. voloshin@ineos.ac.ru., Belov AS, Novikov VV, Vologzhanina AV, Romanenko GV, Budnikova YG, Zelinskii GE, Buzin MI, Voloshin YZ |
| المصدر: |
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2015 Feb 07; Vol. 44 (5), pp. 2476-87. |
| نوع المنشور: |
Journal Article |
| اللغة: |
English |
| بيانات الدورية: |
Publisher: Royal Society of Chemistry Country of Publication: England NLM ID: 101176026 Publication Model: Print Cited Medium: Internet ISSN: 1477-9234 (Electronic) Linking ISSN: 14779226 NLM ISO Abbreviation: Dalton Trans Subsets: PubMed not MEDLINE |
| أسماء مطبوعة: |
Original Publication: Cambridge, UK : Royal Society of Chemistry, c2003- |
| مستخلص: |
Template condensation of dibromoglyoxime with n-butylboronic acid on the corresponding metal ion as a matrix under vigorous reaction conditions afforded iron and cobalt(ii) hexabromoclathrochelates. The paramagnetic cobalt clathrochelate was found to be a low-spin complex at temperatures below 100 K, with a gradual increase in the effective magnetic moment at higher temperatures due to the temperature 1/2↔3/2 spin crossover and a gap caused by the structure phase transition. The multitemperature X-ray and DSC studies of this complex and its iron(ii)-containing analog also showed temperature structural transitions. The variation of an encapsulated metal ion's radius, electronic structure and spin state caused substantial differences in the geometry of its coordination polyhedron; these differences increase with the decrease in temperature due to Jahn-Teller distortion of the encapsulated cobalt(ii) ion with an electronic configuration d(7). As follows from CV and GC data, these cage iron and cobalt complexes undergo both oxidation and reduction quasireversibly, and showed an electrocatalytic activity for hydrogen production in different producing systems. |
| تواريخ الأحداث: |
Date Created: 20150107 Date Completed: 20150521 Latest Revision: 20150120 |
| رمز التحديث: |
20240628 |
| DOI: |
10.1039/c4dt03082f |
| PMID: |
25559125 |
| قاعدة البيانات: |
MEDLINE |
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