دورية أكاديمية
Crystal structure of di-chlorido-(4,11-dimethyl-1,4,8,11-tetra-aza-bicyclo-[6.6.2]hexa-deca-ne)iron(III) hexa-fluorido-phosphate.
| العنوان: | Crystal structure of di-chlorido-(4,11-dimethyl-1,4,8,11-tetra-aza-bicyclo-[6.6.2]hexa-deca-ne)iron(III) hexa-fluorido-phosphate. |
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| المؤلفون: | Funwie NL; Department of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA., Cain AN; Department of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA., Fanning BZ; Department of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA., Hageman SA; Department of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA., Mullens M; Department of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA., Roberts TK; Department of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA., Turner DJ; Department of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA., Valdez CN; Department of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA., Vaughan RW; Department of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA., Ermias HG; Department of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA., Silversides JD; Department of Chemistry, University of Hull, Cottingham Road, Hull, HU6 7RX, England., Archibald SJ; Department of Chemistry, University of Hull, Cottingham Road, Hull, HU6 7RX, England., Hubin TJ; Department of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA., Prior TJ; Department of Chemistry, University of Hull, Cottingham Road, Hull, HU6 7RX, England. |
| المصدر: | Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2015 Aug 26; Vol. 71 (Pt 9), pp. 1073-6. Date of Electronic Publication: 2015 Aug 26 (Print Publication: 2015). |
| نوع المنشور: | Journal Article |
| اللغة: | English |
| بيانات الدورية: | Publisher: John Wiley & Sons Ltd Country of Publication: England NLM ID: 101648987 Publication Model: eCollection Cited Medium: Print ISSN: 2056-9890 (Print) NLM ISO Abbreviation: Acta Crystallogr E Crystallogr Commun Subsets: PubMed not MEDLINE |
| أسماء مطبوعة: | Original Publication: West Sussex : John Wiley & Sons Ltd. [2015]- |
| مستخلص: | The title compound, [FeCl2(C14H30N4)]PF6, contains Fe(3+) coordinated by the four nitro-gen atoms of an ethyl-ene cross-bridged cyclam macrocycle and two cis chloride ligands in a distorted octa-hedral environment. In contrast to other similar compounds this is a monomer. Inter-molecular C-H⋯Cl inter-actions exist in the structure between the complex ions. Comparison with the mononuclear Fe(2+) complex of the same ligand shows that the smaller Fe(3+) ion is more fully engulfed by the cavity of the bicyclic ligand. Comparison with the μ-oxido dinuclear complex of an unsubstituted ligand of the same size demonstrates that the methyl groups of 4,11-dimethyl-1,4,8,11-tetra-aza-bicyclo-[6.6.2]hexa-decane prevent dimerization upon oxidation. |
| References: | Chem Rev. 1996 Nov 7;96(7):2625-2658. (PMID: 11848839) Inorg Chem. 2015 Mar 2;54(5):2221-34. (PMID: 25671291) Inorg Chem. 2006 Apr 17;45(8):3467-74. (PMID: 16602808) Inorg Chem. 2001 Jan 29;40(3):435-44. (PMID: 11209599) Acta Crystallogr C. 2006 Nov;62(Pt 11):m553-5. (PMID: 17088625) Inorg Chem. 2015 Aug 17;54(16):7828-39. (PMID: 26244657) Science. 1993 Jun 4;260(5113):1482-6. (PMID: 8502991) Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. (PMID: 18156677) |
| فهرسة مساهمة: | Keywords: cross bridge; crystal structure; cylam; iron; macrocycle |
| تواريخ الأحداث: | Date Created: 20150924 Date Completed: 20150923 Latest Revision: 20231111 |
| رمز التحديث: | 20240628 |
| مُعرف محوري في PubMed: | PMC4555389 |
| DOI: | 10.1107/S2056989015015340 |
| PMID: | 26396852 |
| قاعدة البيانات: | MEDLINE |
Full Text Finder | تدمد: | 2056-9890 |
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| DOI: | 10.1107/S2056989015015340 |