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Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex.

التفاصيل البيبلوغرافية
العنوان: Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex.
المؤلفون: Wang B; Department of Chemistry and Nano Science, Center for Biomimetic Systems, Ewha Womans University, Seoul 03760, Korea., Lee YM; Department of Chemistry and Nano Science, Center for Biomimetic Systems, Ewha Womans University, Seoul 03760, Korea., Tcho WY; Department of Chemistry and Nano Science, Center for Biomimetic Systems, Ewha Womans University, Seoul 03760, Korea., Tussupbayev S; Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS), Daejeon 34141, Korea.; Department of Chemistry, Korea Advanced Institute of Science and Technology, Daejeon 34141, Korea., Kim ST; Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS), Daejeon 34141, Korea.; Department of Chemistry, Korea Advanced Institute of Science and Technology, Daejeon 34141, Korea., Kim Y; Western Seoul Center, Korea Basic Science Institute, Seoul 03759, Korea., Seo MS; Department of Chemistry and Nano Science, Center for Biomimetic Systems, Ewha Womans University, Seoul 03760, Korea., Cho KB; Department of Chemistry and Nano Science, Center for Biomimetic Systems, Ewha Womans University, Seoul 03760, Korea., Dede Y; Department of Chemistry, Faculty of Science, Gazi University, Ankara 06500, Turkey., Keegan BC; Department of Chemistry, University of Nevada, Reno, Nevada 89557, USA., Ogura T; Picobiology Institute, Graduate School of Life Science, University of Hyogo, RSC-UH LP Center, Hyogo 679-5148, Japan., Kim SH; Western Seoul Center, Korea Basic Science Institute, Seoul 03759, Korea., Ohta T; Picobiology Institute, Graduate School of Life Science, University of Hyogo, RSC-UH LP Center, Hyogo 679-5148, Japan., Baik MH; Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS), Daejeon 34141, Korea.; Department of Chemistry, Korea Advanced Institute of Science and Technology, Daejeon 34141, Korea., Ray K; Department of Chemistry, Humboldt-Universität zu Berlin, Brook Taylor Strasse 2, Berlin 12489, Germany., Shearer J; Department of Chemistry, University of Nevada, Reno, Nevada 89557, USA., Nam W; Department of Chemistry and Nano Science, Center for Biomimetic Systems, Ewha Womans University, Seoul 03760, Korea.; State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China.
المصدر: Nature communications [Nat Commun] 2017 Mar 24; Vol. 8, pp. 14839. Date of Electronic Publication: 2017 Mar 24.
نوع المنشور: Journal Article; Research Support, Non-U.S. Gov't
اللغة: English
بيانات الدورية: Publisher: Nature Pub. Group Country of Publication: England NLM ID: 101528555 Publication Model: Electronic Cited Medium: Internet ISSN: 2041-1723 (Electronic) Linking ISSN: 20411723 NLM ISO Abbreviation: Nat Commun Subsets: PubMed not MEDLINE
أسماء مطبوعة: Original Publication: [London] : Nature Pub. Group
مستخلص: Terminal cobalt(IV)-oxo (Co IV -O) species have been implicated as key intermediates in various cobalt-mediated oxidation reactions. Herein we report the photocatalytic generation of a mononuclear non-haem [(13-TMC)Co IV (O)] 2+ (2) by irradiating [Co II (13-TMC)(CF 3 SO 3 )] + (1) in the presence of [Ru II (bpy) 3 ] 2+ , Na 2 S 2 O 8 , and water as an oxygen source. The intermediate 2 was also obtained by reacting 1 with an artificial oxidant (that is, iodosylbenzene) and characterized by various spectroscopic techniques. In particular, the resonance Raman spectrum of 2 reveals a diatomic Co-O vibration band at 770 cm -1 , which provides the conclusive evidence for the presence of a terminal Co-O bond. In reactivity studies, 2 was shown to be a competent oxidant in an intermetal oxygen atom transfer, C-H bond activation and olefin epoxidation reactions. The present results lend strong credence to the intermediacy of Co IV -O species in cobalt-catalysed oxidation of organic substrates as well as in the catalytic oxidation of water that evolves molecular oxygen.
References: ChemSusChem. 2015 Mar;8(5):844-52. (PMID: 25641853)
Nat Chem. 2014 Apr;6(4):362-7. (PMID: 24651205)
J Am Chem Soc. 2016 Aug 24;138(33):10654-63. (PMID: 27462828)
J Am Chem Soc. 2016 Aug 31;138(34):11017-30. (PMID: 27515121)
Chem Rev. 2010 Feb 10;110(2):932-48. (PMID: 19769330)
Annu Rev Phys Chem. 1998;49:233-66. (PMID: 15012429)
Chem Sci. 2013 Jan;4(1):282-291. (PMID: 23227304)
J Am Chem Soc. 2014 Oct 8;136(40):13942-58. (PMID: 25215462)
Angew Chem Int Ed Engl. 2014 Sep 22;53(39):10403-7. (PMID: 25081948)
J Am Chem Soc. 2016 Feb 24;138(7):2426-36. (PMID: 26816269)
Science. 2008 Aug 22;321(5892):1072-5. (PMID: 18669820)
Inorg Chem. 2013 May 6;52(9):5236-45. (PMID: 23587023)
ChemSusChem. 2014 Aug;7(8):2070-80. (PMID: 25066264)
Acc Chem Res. 2012 May 15;45(5):767-76. (PMID: 22475039)
Acc Chem Res. 2014 Apr 15;47(4):1146-54. (PMID: 24524675)
Chem Soc Rev. 2016 Mar 7;45(5):1197-210. (PMID: 26690848)
J Am Chem Soc. 2012 Oct 24;134(42):17526-35. (PMID: 22998407)
Inorg Chem. 2011 Jan 17;50(2):614-20. (PMID: 21142119)
Inorg Chem. 2008 Mar 17;47(6):1849-61. (PMID: 18330975)
Chem Rev. 2014 Dec 24;114(24):11863-2001. (PMID: 25354019)
J Am Chem Soc. 2015 Oct 14;137(40):12865-72. (PMID: 26390993)
Science. 2003 Feb 14;299(5609):1037-9. (PMID: 12586936)
Dalton Trans. 2016 Oct 7;45(37):14511-5. (PMID: 27188721)
Angew Chem Int Ed Engl. 2015 Sep 28;54(40):11740-4. (PMID: 26273792)
J Am Chem Soc. 2015 Dec 16;137(49):15460-8. (PMID: 26593692)
Inorg Chem. 2012 Jul 2;51(13):7025-31. (PMID: 22694272)
Nat Commun. 2012 Mar 06;3:720. (PMID: 22395611)
J Biol Chem. 2013 Jun 14;288(24):17074-81. (PMID: 23632017)
Acc Chem Res. 2015 Oct 20;48(10 ):2754-64. (PMID: 26352344)
J Am Chem Soc. 2010 Dec 1;132(47):16977-86. (PMID: 21062059)
Chem Rev. 2010 Feb 10;110(2):1060-81. (PMID: 20143877)
Chem Soc Rev. 2009 Jan;38(1):109-14. (PMID: 19088970)
Angew Chem Int Ed Engl. 2006 Jun 12;45(24):3992-5. (PMID: 16688689)
J Am Chem Soc. 2010 May 26;132(20):6882-3. (PMID: 20433197)
J Am Chem Soc. 2005 Sep 14;127(36):12494-5. (PMID: 16144389)
Angew Chem Int Ed Engl. 2011 Feb 11;50(7):1711-5. (PMID: 21308939)
Chem Rev. 2015 Dec 9;115(23):12974-3005. (PMID: 26151088)
Chem Sci. 2014 Jul 1;5(7):2874-2878. (PMID: 25071930)
Dalton Trans. 2013 Jun 14;42(22):7842-5. (PMID: 23588673)
Inorg Chem. 2001 Apr 23;40(9):2058-64. (PMID: 11304150)
Chem Soc Rev. 2015 Mar 7;44(5):1083-100. (PMID: 25566588)
معلومات مُعتمدة: R15 GM120641 United States GM NIGMS NIH HHS
تواريخ الأحداث: Date Created: 20170325 Date Completed: 20181102 Latest Revision: 20181113
رمز التحديث: 20240628
مُعرف محوري في PubMed: PMC5376677
DOI: 10.1038/ncomms14839
PMID: 28337985
قاعدة البيانات: MEDLINE
الوصف
تدمد:2041-1723
DOI:10.1038/ncomms14839