دورية أكاديمية
Synthesis and characterization of Fe III (μ-OH)Zn II complexes: effects of a second coordination sphere and increase in the chelate ring size on the hydrolysis of a phosphate diester and DNA.
العنوان: | Synthesis and characterization of Fe III (μ-OH)Zn II complexes: effects of a second coordination sphere and increase in the chelate ring size on the hydrolysis of a phosphate diester and DNA. |
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المؤلفون: | Silva GADS; Departamento de Química, Universidade Federal de Santa Catarina, 88040-900 Florianópolis, SC, Brazil. ademir.neves@ufsc.br rosely.peralta@ufsc.br., Amorim AL, Souza B, Gabriel P, Terenzi H, Nordlander E, Neves A, Peralta RA |
المصدر: | Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2017 Aug 29; Vol. 46 (34), pp. 11380-11394. |
نوع المنشور: | Journal Article |
اللغة: | English |
بيانات الدورية: | Publisher: Royal Society of Chemistry Country of Publication: England NLM ID: 101176026 Publication Model: Print Cited Medium: Internet ISSN: 1477-9234 (Electronic) Linking ISSN: 14779226 NLM ISO Abbreviation: Dalton Trans Subsets: MEDLINE |
أسماء مطبوعة: | Original Publication: Cambridge, UK : Royal Society of Chemistry, c2003- |
مواضيع طبية MeSH: | 2,4-Dinitrophenol/*analogs & derivatives , Chelating Agents/*chemistry , DNA/*chemistry , Iron/*chemistry , Organometallic Compounds/*chemical synthesis , Organophosphates/*chemistry , Zinc/*chemistry, 2,4-Dinitrophenol/chemistry ; Biomimetic Materials/chemical synthesis ; Biomimetic Materials/chemistry ; Chemistry Techniques, Synthetic ; Hydrolases/metabolism ; Hydrolysis ; Ligands ; Models, Molecular ; Molecular Conformation ; Organometallic Compounds/chemistry |
مستخلص: | The synthesis and characterization of three ligands and their respective heterobinuclear Fe III Zn II complexes were carried out, with the goal of mimicking the active site of purple acid phosphatases (PAPs). The ligand 2-hydroxy-3-(((2-hydroxy-5-methyl-3-(((2-(pyridin-2-yl)ethyl)(pyridin-2-ylmethyl)amino)methyl)benzyl)(pyridin-2ylmethyl)amino)methyl)-5-methylbenzaldehyde (H |
المشرفين على المادة: | 0 (Chelating Agents) 0 (Ligands) 0 (Organometallic Compounds) 0 (Organophosphates) 2566-26-9 (2,4-dinitrophenylphosphate) 9007-49-2 (DNA) E1UOL152H7 (Iron) EC 3.- (Hydrolases) J41CSQ7QDS (Zinc) Q13SKS21MN (2,4-Dinitrophenol) |
تواريخ الأحداث: | Date Created: 20170817 Date Completed: 20180810 Latest Revision: 20180810 |
رمز التحديث: | 20221213 |
DOI: | 10.1039/c7dt02035j |
PMID: | 28812750 |
قاعدة البيانات: | MEDLINE |
تدمد: | 1477-9234 |
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DOI: | 10.1039/c7dt02035j |