Homogeneous Catalysis for Sustainable Hydrogen Storage in Formic Acid and Alcohols.

التفاصيل البيبلوغرافية
العنوان:	Homogeneous Catalysis for Sustainable Hydrogen Storage in Formic Acid and Alcohols.
المؤلفون:	Sordakis K; Institute of Chemical Sciences and Engineering , École Polytechnique Fédérale de Lausanne (EPFL), Avenue Forel 2, CH-1015 Lausanne, Switzerland., Tang C; Leibniz-Institut für Katalyse an der Universität Rostock , Albert-Einstein-Straße 29a, D-18059 Rostock, Germany., Vogt LK; Leibniz-Institut für Katalyse an der Universität Rostock , Albert-Einstein-Straße 29a, D-18059 Rostock, Germany., Junge H; Leibniz-Institut für Katalyse an der Universität Rostock , Albert-Einstein-Straße 29a, D-18059 Rostock, Germany., Dyson PJ; Institute of Chemical Sciences and Engineering , École Polytechnique Fédérale de Lausanne (EPFL), Avenue Forel 2, CH-1015 Lausanne, Switzerland., Beller M; Leibniz-Institut für Katalyse an der Universität Rostock , Albert-Einstein-Straße 29a, D-18059 Rostock, Germany., Laurenczy G; Institute of Chemical Sciences and Engineering , École Polytechnique Fédérale de Lausanne (EPFL), Avenue Forel 2, CH-1015 Lausanne, Switzerland.
المصدر:	Chemical reviews [Chem Rev] 2018 Jan 24; Vol. 118 (2), pp. 372-433. Date of Electronic Publication: 2017 Oct 06.
نوع المنشور:	Journal Article; Research Support, Non-U.S. Gov't
اللغة:	English
بيانات الدورية:	Publisher: American Chemical Society Country of Publication: United States NLM ID: 2985134R Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1520-6890 (Electronic) Linking ISSN: 00092665 NLM ISO Abbreviation: Chem Rev Subsets: PubMed not MEDLINE
أسماء مطبوعة:	Publication: Washington, DC : American Chemical Society Original Publication: Easton, Pa. [etc.] American Chemical Society.
مستخلص:	Hydrogen gas is a storable form of chemical energy that could complement intermittent renewable energy conversion. One of the main disadvantages of hydrogen gas arises from its low density, and therefore, efficient handling and storage methods are key factors that need to be addressed to realize a hydrogen-based economy. Storage systems based on liquids, in particular, formic acid and alcohols, are highly attractive hydrogen carriers as they can be made from CO 2 or other renewable materials, they can be used in stationary power storage units such as hydrogen filling stations, and they can be used directly as transportation fuels. However, to bring about a paradigm change in our energy infrastructure, efficient catalytic processes that release the hydrogen from these molecules, as well as catalysts that regenerate these molecules from CO 2 and hydrogen, are required. In this review, we describe the considerable progress that has been made in homogeneous catalysis for these critical reactions, namely, the hydrogenation of CO 2 to formic acid and methanol and the reverse dehydrogenation reactions. The dehydrogenation of higher alcohols available from renewable feedstocks is also described. Key structural features of the catalysts are analyzed, as is the role of additives, which are required in many systems. Particular attention is paid to advances in sustainable catalytic processes, especially to additive-free processes and catalysts based on Earth-abundant metal ions. Mechanistic information is also presented, and it is hoped that this review not only provides an account of the state of the art in the field but also offers insights into how superior catalytic systems can be obtained in the future.
تواريخ الأحداث:	Date Created: 20171007 Date Completed: 20190115 Latest Revision: 20190115
رمز التحديث:	20240628
DOI:	10.1021/acs.chemrev.7b00182
PMID:	28985048
قاعدة البيانات:	MEDLINE

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تدمد:	1520-6890
DOI:	10.1021/acs.chemrev.7b00182