دورية أكاديمية
Addressing the Challenges of Structure Elucidation in Natural Products Possessing the Oxirane Moiety.
| العنوان: | Addressing the Challenges of Structure Elucidation in Natural Products Possessing the Oxirane Moiety. |
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| المؤلفون: | Kutateladze AG; Department of Chemistry and Biochemistry , University of Denver , Denver , Colorado 80208 , United States., Kuznetsov DM; Department of Chemistry and Biochemistry , University of Denver , Denver , Colorado 80208 , United States., Beloglazkina AA; Department of Chemistry and Biochemistry , University of Denver , Denver , Colorado 80208 , United States., Holt T; Department of Chemistry and Biochemistry , University of Denver , Denver , Colorado 80208 , United States. |
| المصدر: | The Journal of organic chemistry [J Org Chem] 2018 Aug 03; Vol. 83 (15), pp. 8341-8352. Date of Electronic Publication: 2018 Jul 10. |
| نوع المنشور: | Journal Article; Research Support, U.S. Gov't, Non-P.H.S. |
| اللغة: | English |
| بيانات الدورية: | Publisher: American Chemical Society Country of Publication: United States NLM ID: 2985193R Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1520-6904 (Electronic) Linking ISSN: 00223263 NLM ISO Abbreviation: J Org Chem Subsets: MEDLINE |
| أسماء مطبوعة: | Publication: Columbus Oh : American Chemical Society Original Publication: Easton, Pa. [etc.] |
| مواضيع طبية MeSH: | Biological Products/*chemistry , Ethylene Oxide/*chemistry, Density Functional Theory ; Models, Molecular ; Molecular Conformation ; Stereoisomerism |
| مستخلص: | NMR data for natural products containing the epoxy moiety have been revisited and reanalyzed with the help of a recently developed parametric/DFT hybrid computational method, DU8+. More than 20 structures needed revision, which points to challenges in NMR solution structure assignment for molecules possessing this structural feature. Among the revised structures are achicretin 2, acremine P, aromaticane I, artanomalide B, botryosphaerihydrofuran, chloroklotzchin, crithmifolide, crotodichogamoin A, emervaridone C, 9α,15-epoxyafricanane, fischambiguine B, grandilobalide B, guaianolide A, guatterfriesols A and B, juncenolide G, roscotane D, secoafricane 7, taccalonolides AJ and AF, and related compounds. |
| معلومات مُعتمدة: | CHE-1665342 International National Science Foundation |
| المشرفين على المادة: | 0 (Biological Products) JJH7GNN18P (Ethylene Oxide) |
| تواريخ الأحداث: | Date Created: 20180619 Date Completed: 20190916 Latest Revision: 20190916 |
| رمز التحديث: | 20231215 |
| DOI: | 10.1021/acs.joc.8b01027 |
| PMID: | 29912559 |
| قاعدة البيانات: | MEDLINE |
Find this issue from the American Chemical Society | تدمد: | 1520-6904 |
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| DOI: | 10.1021/acs.joc.8b01027 |