Broadband Sensitization of Lanthanide Emission with Indium Phosphide Quantum Dots for Visible to Near-Infrared Downshifting.

التفاصيل البيبلوغرافية
العنوان:	Broadband Sensitization of Lanthanide Emission with Indium Phosphide Quantum Dots for Visible to Near-Infrared Downshifting.
المؤلفون:	Swabeck JK; Materials Sciences Division , Lawrence Berkeley National Laboratory , Berkeley , California 94720 , United States.; Department of Chemistry , University of California-Berkeley , Berkeley , California 94720 , United States., Fischer S; Materials Sciences Division , Lawrence Berkeley National Laboratory , Berkeley , California 94720 , United States.; Department of Chemistry , University of California-Berkeley , Berkeley , California 94720 , United States., Bronstein ND; Materials Sciences Division , Lawrence Berkeley National Laboratory , Berkeley , California 94720 , United States.; Department of Chemistry , University of California-Berkeley , Berkeley , California 94720 , United States., Alivisatos AP; Materials Sciences Division , Lawrence Berkeley National Laboratory , Berkeley , California 94720 , United States.; Department of Chemistry , University of California-Berkeley , Berkeley , California 94720 , United States.; Department of Materials Science and Engineering , University of California-Berkeley , Berkeley , California 94720 , United States.; Kavli Energy NanoScience Institute , Berkeley , California 94720 , United States.
المصدر:	Journal of the American Chemical Society [J Am Chem Soc] 2018 Jul 25; Vol. 140 (29), pp. 9120-9126. Date of Electronic Publication: 2018 Jul 13.
نوع المنشور:	Journal Article; Research Support, U.S. Gov't, Non-P.H.S.
اللغة:	English
بيانات الدورية:	Publisher: American Chemical Society Country of Publication: United States NLM ID: 7503056 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1520-5126 (Electronic) Linking ISSN: 00027863 NLM ISO Abbreviation: J Am Chem Soc Subsets: PubMed not MEDLINE
أسماء مطبوعة:	Publication: Washington, DC : American Chemical Society Original Publication: Easton, Pa. [etc.]
مستخلص:	Semiconductor quantum dot (QD)-sensitized lanthanide ions hold great promise in producing a broadly absorbing and sharply emitting luminophore, but their synthesis has proven to be difficult. We report the first synthesis of core/shell/shell InP/Ln x Y 1- x F 3 /ShF 3 (Ln = Yb, Nd; Sh = Lu, Y) nanocrystals that exhibit a broad visible absorption coupled to a sharp near-infrared emission. Additionally, this is the first report of Nd being coupled to a QD absorber. We characterize the system with a variety of electron microscopy and X-ray techniques that prove this unique structure. Optical measurements confirm the correlation of the Ln ³⁺ emission to the QD absorption, while the presence of a trap-state emission gives a clue as to the mechanism of energy transfer between the dot and the lanthanide.
تواريخ الأحداث:	Date Created: 20180621 Latest Revision: 20191120
رمز التحديث:	20240628
DOI:	10.1021/jacs.8b02612
PMID:	29924609
قاعدة البيانات:	MEDLINE

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الوصف
تدمد:	1520-5126
DOI:	10.1021/jacs.8b02612