دورية أكاديمية
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Sodium-coupled electron transfer reactivity of metal-organic frameworks containing titanium clusters: the importance of cations in redox chemistry.

التفاصيل البيبلوغرافية
العنوان: Sodium-coupled electron transfer reactivity of metal-organic frameworks containing titanium clusters: the importance of cations in redox chemistry.
المؤلفون: Saouma CT; Department of Chemistry , University of Washington , Box 351700 , Seattle , Washington 98195-1700 , USA.; Department of Chemistry , University of Utah , 315 S 1400 E , Salt Lake City , Utah 84112-0850 , USA . Email: caroline.saouma@utah.edu., Tsou CC; Department of Chemistry , University of Washington , Box 351700 , Seattle , Washington 98195-1700 , USA.; Department of Chemistry , Yale University , P.O. Box 208107 , New Haven , CT 06520-8107 , USA . Email: james.mayer@yale.edu., Richard S; Department of Chemistry , University of Washington , Box 351700 , Seattle , Washington 98195-1700 , USA., Ameloot R; Centre for Surface Chemistry and Catalysis , KU Leuven , University of Leuven , Celestijnenlaan 200F p.o. box 2461 , 3001 Leuven , Belgium . Email: dirk.devos@kuleuven.be., Vermoortele F; Centre for Surface Chemistry and Catalysis , KU Leuven , University of Leuven , Celestijnenlaan 200F p.o. box 2461 , 3001 Leuven , Belgium . Email: dirk.devos@kuleuven.be., Smolders S; Centre for Surface Chemistry and Catalysis , KU Leuven , University of Leuven , Celestijnenlaan 200F p.o. box 2461 , 3001 Leuven , Belgium . Email: dirk.devos@kuleuven.be., Bueken B; Centre for Surface Chemistry and Catalysis , KU Leuven , University of Leuven , Celestijnenlaan 200F p.o. box 2461 , 3001 Leuven , Belgium . Email: dirk.devos@kuleuven.be., DiPasquale AG; Department of Chemistry , University of California , Latimer Hall , Berkeley , CA 94720 , USA., Kaminsky W; Department of Chemistry , University of Washington , Box 351700 , Seattle , Washington 98195-1700 , USA., Valdez CN; Department of Chemistry , University of Washington , Box 351700 , Seattle , Washington 98195-1700 , USA.; Department of Chemistry , Yale University , P.O. Box 208107 , New Haven , CT 06520-8107 , USA . Email: james.mayer@yale.edu., De Vos DE; Centre for Surface Chemistry and Catalysis , KU Leuven , University of Leuven , Celestijnenlaan 200F p.o. box 2461 , 3001 Leuven , Belgium . Email: dirk.devos@kuleuven.be., Mayer JM; Department of Chemistry , University of Washington , Box 351700 , Seattle , Washington 98195-1700 , USA.; Department of Chemistry , Yale University , P.O. Box 208107 , New Haven , CT 06520-8107 , USA . Email: james.mayer@yale.edu.
المصدر: Chemical science [Chem Sci] 2018 Nov 19; Vol. 10 (5), pp. 1322-1331. Date of Electronic Publication: 2018 Nov 19 (Print Publication: 2019).
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: Royal Society of Chemistry Country of Publication: England NLM ID: 101545951 Publication Model: eCollection Cited Medium: Print ISSN: 2041-6520 (Print) Linking ISSN: 20416520 NLM ISO Abbreviation: Chem Sci Subsets: PubMed not MEDLINE
أسماء مطبوعة: Original Publication: Cambridge, UK : Royal Society of Chemistry, [2010]-
مستخلص: Stoichiometric reduction reactions of two metal-organic frameworks (MOFs) by the solution reagents (M = Cr, Co) are described. The two MOFs contain clusters with Ti 8 O 8 rings: Ti 8 O 8 (OH) 4 (bdc) 6 ; bdc = terephthalate (MIL-125) and Ti 8 O 8 (OH) 4 (bdc-NH 2 ) 6 ; bdc-NH 2 = 2-aminoterephthalate (NH 2 -MIL-125). The stoichiometry of the redox reactions was probed using solution NMR methods. The extent of reduction is greatly enhanced by the presence of Na + , which is incorporated into the bulk of the material. The roughly 1 : 1 stoichiometry of electrons and cations indicates that the storage of e - in the MOF is tightly coupled to a cation within the architecture, for charge balance.
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معلومات مُعتمدة: F32 GM099316 United States GM NIGMS NIH HHS
تواريخ الأحداث: Date Created: 20190228 Latest Revision: 20240714
رمز التحديث: 20240714
مُعرف محوري في PubMed: PMC6354900
DOI: 10.1039/c8sc04138e
PMID: 30809347
قاعدة البيانات: MEDLINE
الوصف
تدمد:2041-6520
DOI:10.1039/c8sc04138e