التفاصيل البيبلوغرافية
| العنوان: |
The self-disproportionation of enantiomers (SDE) of amino acids and their derivatives. |
| المؤلفون: |
Han J; College of Chemical Engineering, Nanjing Forestry University, Nanjing, 210037, China., Wzorek A; Institute of Chemistry, Jan Kochanowski University in Kielce, Świętokrzyska 15G, 25-406, Kielce, Poland.; Department of Organic Chemistry I, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel Lardizábal 3, 20018, San Sebastián, Spain., Kwiatkowska M; Institute of Chemistry, Jan Kochanowski University in Kielce, Świętokrzyska 15G, 25-406, Kielce, Poland., Soloshonok VA; Department of Organic Chemistry I, Faculty of Chemistry, University of the Basque Country UPV/EHU, Paseo Manuel Lardizábal 3, 20018, San Sebastián, Spain. vadym.soloshonok@ehu.es.; IKERBASQUE, Basque Foundation for Science, María Díaz de Haro 3, Plaza Bizkaia, 48013, Bilbao, Spain. vadym.soloshonok@ehu.es., Klika KD; Molecular Structure Analysis, German Cancer Research Center (DKFZ), Im Neuenheimer Feld 280, 69120, Heidelberg, Germany. k.klika@dkfz.de. |
| المصدر: |
Amino acids [Amino Acids] 2019 Jun; Vol. 51 (6), pp. 865-889. Date of Electronic Publication: 2019 Mar 22. |
| نوع المنشور: |
Journal Article; Review |
| اللغة: |
English |
| بيانات الدورية: |
Publisher: Springer-Verlag Country of Publication: Austria NLM ID: 9200312 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1438-2199 (Electronic) Linking ISSN: 09394451 NLM ISO Abbreviation: Amino Acids Subsets: MEDLINE |
| أسماء مطبوعة: |
Original Publication: Wien ; New York : Springer-Verlag, c1991- |
| مواضيع طبية MeSH: |
Sublimation, Chemical*, Amino Acids/*chemistry, Chemical Fractionation ; Chromatography ; Crystallization ; Stereoisomerism |
| مستخلص: |
This review covers the phenomenon of the self-disproportionation of enantiomers (SDE) of amino acids and their derivatives in all its guises from phase transformations (recrystallization, sublimation, and distillation), to the application of force fields, through to chromatography including HPLC, MPLC, gravity-driven column chromatography, and SEC. The relevance of the SDE phenomenon to amino acid research and to marketed pharmaceuticals is clear given the potential for alteration of the enantiomeric excess of a portion of a scalemic sample. In addition, the possible contribution of the SDE phenomenon to the genesis of prebiotic homochirality is considered. |
| معلومات مُعتمدة: |
21761132021 National Natural Science Foundation of China; 612 561 Ministry of Science and Higher Education, Poland |
| فهرسة مساهمة: |
Keywords: Achiral chromatography; Amino acids and derivatives; Enantioenrichment/-depletion/-purification; Molecular chirality; Physicochemical phase transitions; Self-disproportionation of enantiomers (SDE) |
| المشرفين على المادة: |
0 (Amino Acids) |
| تواريخ الأحداث: |
Date Created: 20190324 Date Completed: 20191119 Latest Revision: 20191119 |
| رمز التحديث: |
20240628 |
| DOI: |
10.1007/s00726-019-02729-y |
| PMID: |
30903285 |
| قاعدة البيانات: |
MEDLINE |
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