دورية أكاديمية
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An original recycling method for Li-ion batteries through large scale production of Metal Organic Frameworks.

التفاصيل البيبلوغرافية
العنوان: An original recycling method for Li-ion batteries through large scale production of Metal Organic Frameworks.
المؤلفون: Cognet M; ICSM (UMR 5257), CEA, CNRS, ENSCM, Univ Montpellier, Bagnols-sur-Cèze 30207, France., Condomines J; ICSM (UMR 5257), CEA, CNRS, ENSCM, Univ Montpellier, Bagnols-sur-Cèze 30207, France., Cambedouzou J; ICSM (UMR 5257), CEA, CNRS, ENSCM, Univ Montpellier, Bagnols-sur-Cèze 30207, France., Madhavi S; School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore; Energy Research Institute @ NTU, Nanyang Technological University, 50 Nanyang Drive, Singapore, Singapore., Carboni M; ICSM (UMR 5257), CEA, CNRS, ENSCM, Univ Montpellier, Bagnols-sur-Cèze 30207, France. Electronic address: michael.carboni@cea.fr., Meyer D; ICSM (UMR 5257), CEA, CNRS, ENSCM, Univ Montpellier, Bagnols-sur-Cèze 30207, France.
المصدر: Journal of hazardous materials [J Hazard Mater] 2020 Mar 05; Vol. 385, pp. 121603. Date of Electronic Publication: 2019 Nov 05.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: Elsevier Country of Publication: Netherlands NLM ID: 9422688 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1873-3336 (Electronic) Linking ISSN: 03043894 NLM ISO Abbreviation: J Hazard Mater Subsets: PubMed not MEDLINE; MEDLINE
أسماء مطبوعة: Original Publication: Amsterdam : Elsevier,
مستخلص: A concept is proposed for the recycling of Li-ion batteries with an open-loop method that allows to reduce the volume of wastes and simultaneously to produce valuable materials in large amounts (Metal-Organic Frameworks, MOFs). After dissolution of Nickel, Manganese, Cobalt (NMC) batteries in acidic solution (HCl, HNO 3 or H 2 SO 4 /H 2 O 2 ), addition of organic moieties and a heat treatment, different MOFs are obtained. Solutions after precipitation are analyzed by inductively coupled plasma and materials are characterized by powder X-Ray diffraction, N 2 adsorption, thermogravimetric analysis and Scanning electron microscope. With the use of Benzene-Tri-Carboxylic Acid as ligand, it has been possible to form selectively a MOF, based on Al metallic nodes, called MIL-96 in the literature, and known for its interesting properties in gas storage applications. The supernatant is then used again to precipitate other metals as MOFs after addition of a second batch of ligands. These two other MOFs are based on Cu (known as HKUST-1 in the literature) or Ni-Mn (with a new crystalline structure) depending of conditions. This method shows promising results at the lab scale (15 g of wastes can be converted in 10 g of MOFs), and opens interesting perspectives for the scaled-up production of MOFs.
(Copyright © 2019 Elsevier B.V. All rights reserved.)
فهرسة مساهمة: Keywords: Hydrometallurgy process; Lithium-ion battery; Metal Organic Frameworks; Recycling; Selective precipitation
تواريخ الأحداث: Date Created: 20191120 Latest Revision: 20200304
رمز التحديث: 20240628
DOI: 10.1016/j.jhazmat.2019.121603
PMID: 31740305
قاعدة البيانات: MEDLINE
الوصف
تدمد:1873-3336
DOI:10.1016/j.jhazmat.2019.121603