دورية أكاديمية
أعرض في EDS

Conversion of Ethanol to 2-Ethylhexenal at Ambient Conditions Using Tandem, Biphasic Catalysis.

التفاصيل البيبلوغرافية
العنوان: Conversion of Ethanol to 2-Ethylhexenal at Ambient Conditions Using Tandem, Biphasic Catalysis.
المؤلفون: Hafenstine GR; Department of Chemical and Biological Engineering, University of Colorado Boulder, 3145 Colorado Avenue, 596 UCB, Boulder, Colorado 80303, United States., Harris AW; Department of Chemical and Biological Engineering, University of Colorado Boulder, 3145 Colorado Avenue, 596 UCB, Boulder, Colorado 80303, United States., Ma K; Department of Chemical and Biological Engineering, University of Colorado Boulder, 3145 Colorado Avenue, 596 UCB, Boulder, Colorado 80303, United States., Cha JN; Department of Chemical and Biological Engineering, University of Colorado Boulder, 3145 Colorado Avenue, 596 UCB, Boulder, Colorado 80303, United States.; Materials Science and Engineering Program, University of Colorado Boulder, 3145 Colorado Avenue, 596 UCB, Boulder, Colorado 80303, United States., Goodwin AP; Department of Chemical and Biological Engineering, University of Colorado Boulder, 3145 Colorado Avenue, 596 UCB, Boulder, Colorado 80303, United States.; Materials Science and Engineering Program, University of Colorado Boulder, 3145 Colorado Avenue, 596 UCB, Boulder, Colorado 80303, United States.
المصدر: ACS sustainable chemistry & engineering [ACS Sustain Chem Eng] 2017; Vol. 5 (11), pp. 10483-10489. Date of Electronic Publication: 2017 Oct 04.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: American Chemical Society Country of Publication: United States NLM ID: 101608852 Publication Model: Print-Electronic Cited Medium: Print ISSN: 2168-0485 (Print) Linking ISSN: 21680485 NLM ISO Abbreviation: ACS Sustain Chem Eng Subsets: PubMed not MEDLINE
أسماء مطبوعة: Original Publication: Washington, DC : American Chemical Society, c2013-
مستخلص: Ethanol is a ubiquitous fermentation product well-tolerated by microbes, but purification from growth media requires multiple distillations or other energy intensive processes. Converting such metabolites to larger, hydrophobic products would both yield higher energy products and facilitate separation. Here, we demonstrate the conversion of C 2 ethanol to C 8 2-ethylhexenal via a sequential oxidation-aldol-hydrogenation-aldol process with solar energy as the only required input. Photocatalysis was utilized to drive enzymatic oxidation of ethanol, while biphasic media in conjunction with aldol coupling and Pd assisted hydrogenation kept the oxidation and reduction processes physically and chemically separated. Using this process, 2-ethylhexenal was produced from ethanol in both buffer and diluted yeast media.
References: Science. 2010 Aug 13;329(5993):796-9. (PMID: 20705853)
Science. 2007 Jul 20;317(5836):355-8. (PMID: 17641197)
J Phys Chem A. 2008 Apr 3;112(13):2827-37. (PMID: 18314969)
Curr Opin Biotechnol. 2010 Jun;21(3):277-86. (PMID: 20399634)
Angew Chem Int Ed Engl. 2015 Sep 21;54(39):11490-4. (PMID: 26136433)
Nat Mater. 2014 Nov;13(11):1013-8. (PMID: 25087066)
J Am Chem Soc. 2005 Feb 23;127(7):2172-83. (PMID: 15713095)
Curr Opin Biotechnol. 2011 Jun;22(3):337-43. (PMID: 21367598)
Curr Opin Biotechnol. 2014 Jun;27:79-87. (PMID: 24863900)
ACS Sustain Chem Eng. 2016 Mar 7;4(3):671-675. (PMID: 28480149)
FEMS Yeast Res. 2002 Dec;2(4):481-94. (PMID: 12702265)
Appl Environ Microbiol. 1988 Jul;54(7):1662-7. (PMID: 16347676)
Biochem J. 1975 May;147(2):303-11. (PMID: 241323)
Science. 2007 Feb 9;315(5813):801-4. (PMID: 17289987)
J Am Chem Soc. 2015 Jan 28;137(3):1362-71. (PMID: 25603470)
Curr Opin Chem Biol. 2015 Dec;29:40-8. (PMID: 26360875)
Org Lett. 2012 Jan 6;14(1):422-5. (PMID: 22182221)
Science. 2012 Jan 20;335(6066):308-13. (PMID: 22267807)
Small. 2015 Feb 11;11(6):668-74. (PMID: 25238557)
FEMS Microbiol Lett. 2016 May;363(9):. (PMID: 27020411)
Nat Chem Biol. 2011 Apr;7(4):222-7. (PMID: 21358636)
Curr Opin Biotechnol. 2013 Dec;24(6):1044-53. (PMID: 23541503)
Nano Lett. 2016 Mar 9;16(3):1776-81. (PMID: 26788824)
J Biol Chem. 1950 May;184(1):313-9. (PMID: 15443900)
Chem Rev. 2010 Nov 10;110(11):6446-73. (PMID: 21062097)
ACS Catal. 2017;7(1):568-572. (PMID: 33133753)
Nature. 2012 Aug 16;488(7411):320-8. (PMID: 22895337)
Angew Chem Int Ed Engl. 2014 Jul 21;53(30):7785-8. (PMID: 24916924)
Biotechnol Prog. 1999 Jul-Aug;15(4):594-602. (PMID: 10441349)
Appl Environ Microbiol. 2013 Jan;79(1):91-104. (PMID: 23064336)
معلومات مُعتمدة: DP2 EB020401 United States EB NIBIB NIH HHS
فهرسة مساهمة: Keywords: Enzyme catalysis; Green chemistry; Heterogeneous catalysis; Nonequilibrium processes; Photocatalysis; Prganocatalysis
تواريخ الأحداث: Date Created: 20201123 Latest Revision: 20201125
رمز التحديث: 20231215
مُعرف محوري في PubMed: PMC7678241
DOI: 10.1021/acssuschemeng.7b02487
PMID: 33224638
قاعدة البيانات: MEDLINE
الوصف
تدمد:2168-0485
DOI:10.1021/acssuschemeng.7b02487