دورية أكاديمية
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Binding Interactions in Copper, Silver and Gold π-Complexes.

التفاصيل البيبلوغرافية
العنوان: Binding Interactions in Copper, Silver and Gold π-Complexes.
المؤلفون: Mehara J; Department of Spectroscopy and Catalysis, Institute for Molecules and Materials, Radboud University Nijmegen, Heyendaalseweg 135, 6525 AJ, Nijmegen (The, Netherlands., Watson BT; Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, Texas, 76019, USA., Noonikara-Poyil A; Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, Texas, 76019, USA., Zacharias AO; Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, Texas, 76019, USA., Roithová J; Department of Spectroscopy and Catalysis, Institute for Molecules and Materials, Radboud University Nijmegen, Heyendaalseweg 135, 6525 AJ, Nijmegen (The, Netherlands., Rasika Dias HV; Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, Texas, 76019, USA.
المصدر: Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2022 Mar 01; Vol. 28 (13), pp. e202103984. Date of Electronic Publication: 2022 Feb 08.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 9513783 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1521-3765 (Electronic) Linking ISSN: 09476539 NLM ISO Abbreviation: Chemistry Subsets: MEDLINE
أسماء مطبوعة: Original Publication: Weinheim, Germany : Wiley-VCH
مواضيع طبية MeSH: Copper*/chemistry , Silver*/chemistry, Crystallography, X-Ray ; Gold/chemistry ; Ligands
مستخلص: The copper(I), silver(I), and gold(I) metals bind π-ligands by σ-bonding and π-back bonding interactions. These interactions were investigated using bidentate ancillary ligands with electron donating and withdrawing substituents. The π-ligands span from ethylene to larger terminal and internal alkenes and alkynes. Results of X-ray crystallography, NMR, and IR spectroscopy and gas phase experiments show that the binding energies increase in the order Ag (© 2022 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.)
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معلومات مُعتمدة: 682275 H2020 European Research Council; CHE-1954456 Integrative and Collaborative Education and Research; Y-1289 Welch Foundation
فهرسة مساهمة: Keywords: X-ray diffraction; alkene ligands; alkyne ligands; bond energy; mass spectrometry
المشرفين على المادة: 0 (Ligands)
3M4G523W1G (Silver)
7440-57-5 (Gold)
789U1901C5 (Copper)
تواريخ الأحداث: Date Created: 20220125 Date Completed: 20220302 Latest Revision: 20220731
رمز التحديث: 20221213
مُعرف محوري في PubMed: PMC9305286
DOI: 10.1002/chem.202103984
PMID: 35076112
قاعدة البيانات: MEDLINE
الوصف
تدمد:1521-3765
DOI:10.1002/chem.202103984