التفاصيل البيبلوغرافية
| العنوان: |
Phosphorescent biaryl platinum(IV) complexes obtained through double metalation of dibenzoiodolium ions. |
| المؤلفون: |
López-López JC; Departamento de Química Inorgánica, Facultad de Química, Universidad de Murcia, Campus de Espinardo, 19, 30100 Murcia, Spain. pgh@um.es., Bautista D; Área Científica y Técnica de Investigación, Universidad de Murcia, Campus de Espinardo, 21, 30100 Murcia, Spain., González-Herrero P; Departamento de Química Inorgánica, Facultad de Química, Universidad de Murcia, Campus de Espinardo, 19, 30100 Murcia, Spain. pgh@um.es. |
| المصدر: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2022 Apr 05; Vol. 58 (28), pp. 4532-4535. Date of Electronic Publication: 2022 Apr 05. |
| نوع المنشور: |
Journal Article |
| اللغة: |
English |
| بيانات الدورية: |
Publisher: Royal Society of Chemistry Country of Publication: England NLM ID: 9610838 Publication Model: Electronic Cited Medium: Internet ISSN: 1364-548X (Electronic) Linking ISSN: 13597345 NLM ISO Abbreviation: Chem Commun (Camb) Subsets: PubMed not MEDLINE; MEDLINE |
| أسماء مطبوعة: |
Original Publication: Cambridge : Royal Society of Chemistry |
| مستخلص: |
The first series of neutral, tris-chelate, phosphorecent Pt(IV) complexes is reported, which combine two cyclometalated 2-arylpyridine ligands and a dimetalated biaryl. The introduction of biaryl ligands is achieved under mild conditions through the oxidative addition of dibenzoiodolium ions to Pt(II) precursors to give Pt(IV) intermediates with a singly metalated 2-(2-iodoaryl)aryl ligand, followed by the reductive metalation of the C-I bond. The modulation of emission characteristics via derivatization of both types of ligands is demonstrated. |
| تواريخ الأحداث: |
Date Created: 20220318 Latest Revision: 20220405 |
| رمز التحديث: |
20240628 |
| DOI: |
10.1039/d2cc01018f |
| PMID: |
35302577 |
| قاعدة البيانات: |
MEDLINE |
