Molybdenum Carbide Electrocatalyst In Situ Embedded in Porous Nitrogen-Rich Carbon Nanotubes Promotes Rapid Kinetics in Sodium-Metal-Sulfur Batteries.

التفاصيل البيبلوغرافية
العنوان:	Molybdenum Carbide Electrocatalyst In Situ Embedded in Porous Nitrogen-Rich Carbon Nanotubes Promotes Rapid Kinetics in Sodium-Metal-Sulfur Batteries.
المؤلفون:	Hao H; Materials Science and Engineering Program and Texas Materials Institute (TMI), The University of Texas at Austin, Austin, TX, 78712-1591, USA., Wang Y; Materials Science and Engineering Program and Texas Materials Institute (TMI), The University of Texas at Austin, Austin, TX, 78712-1591, USA., Katyal N; Department of Chemistry, The University of Texas at Austin, Austin, TX, 78712, USA., Yang G; Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37830, USA., Dong H; Materials Science and Engineering Program and Texas Materials Institute (TMI), The University of Texas at Austin, Austin, TX, 78712-1591, USA., Liu P; Materials Science and Engineering Program and Texas Materials Institute (TMI), The University of Texas at Austin, Austin, TX, 78712-1591, USA., Hwang S; Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY, 11973, USA., Mantha J; Department of Chemistry, The University of Texas at Austin, Austin, TX, 78712, USA., Henkelman G; Department of Chemistry, The University of Texas at Austin, Austin, TX, 78712, USA., Xu Y; Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY, 11973, USA.; Materials Science and Chemical Engineering Department, Stony Brook University, Stony Brook, NY, 11790, USA., Boscoboinik JA; Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY, 11973, USA., Nanda J; Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37830, USA., Mitlin D; Materials Science and Engineering Program and Texas Materials Institute (TMI), The University of Texas at Austin, Austin, TX, 78712-1591, USA.
المصدر:	Advanced materials (Deerfield Beach, Fla.) [Adv Mater] 2022 Jul; Vol. 34 (26), pp. e2106572. Date of Electronic Publication: 2022 May 23.
نوع المنشور:	Journal Article
اللغة:	English
بيانات الدورية:	Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 9885358 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1521-4095 (Electronic) Linking ISSN: 09359648 NLM ISO Abbreviation: Adv Mater Subsets: PubMed not MEDLINE; MEDLINE
أسماء مطبوعة:	Publication: Sept. 3, 1997- : Weinheim : Wiley-VCH Original Publication: Deerfield Beach, FL : VCH Publishers, 1989-
مستخلص:	This is the first report of molybdenum carbide-based electrocatalyst for sulfur-based sodium-metal batteries. MoC/Mo 2 C is in situ grown on nitrogen-doped carbon nanotubes in parallel with formation of extensive nanoporosity. Sulfur impregnation (50 wt% S) results in unique triphasic architecture termed molybdenum carbide-porous carbon nanotubes host (MoC/Mo 2 C@PCNT-S). Quasi-solid-state phase transformation to Na 2 S is promoted in carbonate electrolyte, with in situ time-resolved Raman, X-ray photoelectron spectroscopy, and optical analyses demonstrating minimal soluble polysulfides. MoC/Mo 2 C@PCNT-S cathodes deliver among the most promising rate performance characteristics in the literature, achieving 987 mAh g ^-1 at 1 A g ^-1 , 818 mAh g ^-1 at 3 A g ^-1 , and 621 mAh g ^-1 at 5 A g ^-1 . The cells deliver superior cycling stability, retaining 650 mAh g ^-1 after 1000 cycles at 1.5 A g ^-1 , corresponding to 0.028% capacity decay per cycle. High mass loading cathodes (64 wt% S, 12.7 mg cm ^-2 ) also show cycling stability. Density functional theory demonstrates that formation energy of Na 2 S x (1 ≤ x ≤ 4) on surface of MoC/Mo 2 C is significantly lowered compared to analogous redox in liquid. Strong binding of Na 2 S x (1 ≤ x ≤ 4) on MoC/Mo 2 C surfaces results from charge transfer between the sulfur and Mo sites on carbides' surface. (© 2022 Wiley-VCH GmbH.)
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معلومات مُعتمدة:	Energy Storage Program; DE-AC05 00OR22725 Office of Electricity; National Science Foundation; 1938833 Division of Materials Research; F-1841 Welch Foundation
فهرسة مساهمة:	Keywords: Na-S batteries; electrocatalysis; molybdenum carbide catalyst; porous carbon
تواريخ الأحداث:	Date Created: 20220422 Latest Revision: 20220701
رمز التحديث:	20240628
DOI:	10.1002/adma.202106572
PMID:	35451133
قاعدة البيانات:	MEDLINE

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تدمد:	1521-4095
DOI:	10.1002/adma.202106572