دورية أكاديمية

Catalytic Asymmetric Umpolung Tandem Reactions of Hemiacetals via Dinuclear Zinc Cooperative Catalysis.

التفاصيل البيبلوغرافية
العنوان: Catalytic Asymmetric Umpolung Tandem Reactions of Hemiacetals via Dinuclear Zinc Cooperative Catalysis.
المؤلفون: Xing SN; College of Chemistry and Institute of Green Catalysis, Zhengzhou University, No. 100, Science Road, Zhengzhou City, Henan 450000, P. R. China., Hua YZ; College of Chemistry and Institute of Green Catalysis, Zhengzhou University, No. 100, Science Road, Zhengzhou City, Henan 450000, P. R. China., Yang XC; College of Chemistry and Institute of Green Catalysis, Zhengzhou University, No. 100, Science Road, Zhengzhou City, Henan 450000, P. R. China., Du SS; College of Chemistry and Institute of Green Catalysis, Zhengzhou University, No. 100, Science Road, Zhengzhou City, Henan 450000, P. R. China., Jia SK; College of Chemistry and Institute of Green Catalysis, Zhengzhou University, No. 100, Science Road, Zhengzhou City, Henan 450000, P. R. China., Mei GJ; College of Chemistry and Institute of Green Catalysis, Zhengzhou University, No. 100, Science Road, Zhengzhou City, Henan 450000, P. R. China., Wang MC; College of Chemistry and Institute of Green Catalysis, Zhengzhou University, No. 100, Science Road, Zhengzhou City, Henan 450000, P. R. China.
المصدر: Organic letters [Org Lett] 2022 Jun 10; Vol. 24 (22), pp. 3909-3914. Date of Electronic Publication: 2022 Apr 25.
نوع المنشور: Journal Article; Research Support, Non-U.S. Gov't
اللغة: English
بيانات الدورية: Publisher: American Chemical Society Country of Publication: United States NLM ID: 100890393 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1523-7052 (Electronic) Linking ISSN: 15237052 NLM ISO Abbreviation: Org Lett Subsets: MEDLINE
أسماء مطبوعة: Original Publication: Washington, DC : American Chemical Society, c1999-
مواضيع طبية MeSH: Carbon* , Zinc*, Catalysis
مستخلص: The umpolung activity of hemiacetals serving as α-carbon nucleophiles has been reported via dinuclear zinc cooperative catalysis. This umpolung strategy has been applied to catalytic asymmetric tandem reactions of 1-tosylindoline-2,3-diols with β,γ-unsaturated-α-keto compounds, providing a broad series of structurally diverse tetrahydrofuran spirooxindoles and dihydrofurans, respectively. In addition, products could be transformed to quinazoline and quinoline derivatives.
المشرفين على المادة: 7440-44-0 (Carbon)
J41CSQ7QDS (Zinc)
تواريخ الأحداث: Date Created: 20220425 Date Completed: 20220613 Latest Revision: 20220619
رمز التحديث: 20240628
DOI: 10.1021/acs.orglett.2c00913
PMID: 35467355
قاعدة البيانات: MEDLINE
الوصف
تدمد:1523-7052
DOI:10.1021/acs.orglett.2c00913