دورية أكاديمية
Catalytic Asymmetric Umpolung Tandem Reactions of Hemiacetals via Dinuclear Zinc Cooperative Catalysis.
العنوان: | Catalytic Asymmetric Umpolung Tandem Reactions of Hemiacetals via Dinuclear Zinc Cooperative Catalysis. |
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المؤلفون: | Xing SN; College of Chemistry and Institute of Green Catalysis, Zhengzhou University, No. 100, Science Road, Zhengzhou City, Henan 450000, P. R. China., Hua YZ; College of Chemistry and Institute of Green Catalysis, Zhengzhou University, No. 100, Science Road, Zhengzhou City, Henan 450000, P. R. China., Yang XC; College of Chemistry and Institute of Green Catalysis, Zhengzhou University, No. 100, Science Road, Zhengzhou City, Henan 450000, P. R. China., Du SS; College of Chemistry and Institute of Green Catalysis, Zhengzhou University, No. 100, Science Road, Zhengzhou City, Henan 450000, P. R. China., Jia SK; College of Chemistry and Institute of Green Catalysis, Zhengzhou University, No. 100, Science Road, Zhengzhou City, Henan 450000, P. R. China., Mei GJ; College of Chemistry and Institute of Green Catalysis, Zhengzhou University, No. 100, Science Road, Zhengzhou City, Henan 450000, P. R. China., Wang MC; College of Chemistry and Institute of Green Catalysis, Zhengzhou University, No. 100, Science Road, Zhengzhou City, Henan 450000, P. R. China. |
المصدر: | Organic letters [Org Lett] 2022 Jun 10; Vol. 24 (22), pp. 3909-3914. Date of Electronic Publication: 2022 Apr 25. |
نوع المنشور: | Journal Article; Research Support, Non-U.S. Gov't |
اللغة: | English |
بيانات الدورية: | Publisher: American Chemical Society Country of Publication: United States NLM ID: 100890393 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1523-7052 (Electronic) Linking ISSN: 15237052 NLM ISO Abbreviation: Org Lett Subsets: MEDLINE |
أسماء مطبوعة: | Original Publication: Washington, DC : American Chemical Society, c1999- |
مواضيع طبية MeSH: | Carbon* , Zinc*, Catalysis |
مستخلص: | The umpolung activity of hemiacetals serving as α-carbon nucleophiles has been reported via dinuclear zinc cooperative catalysis. This umpolung strategy has been applied to catalytic asymmetric tandem reactions of 1-tosylindoline-2,3-diols with β,γ-unsaturated-α-keto compounds, providing a broad series of structurally diverse tetrahydrofuran spirooxindoles and dihydrofurans, respectively. In addition, products could be transformed to quinazoline and quinoline derivatives. |
المشرفين على المادة: | 7440-44-0 (Carbon) J41CSQ7QDS (Zinc) |
تواريخ الأحداث: | Date Created: 20220425 Date Completed: 20220613 Latest Revision: 20220619 |
رمز التحديث: | 20240628 |
DOI: | 10.1021/acs.orglett.2c00913 |
PMID: | 35467355 |
قاعدة البيانات: | MEDLINE |
تدمد: | 1523-7052 |
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DOI: | 10.1021/acs.orglett.2c00913 |