دورية أكاديمية
Deuterium equilibrium isotope effects in a supramolecular receptor for the hydrochalcogenide and halide anions.
| العنوان: | Deuterium equilibrium isotope effects in a supramolecular receptor for the hydrochalcogenide and halide anions. |
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| المؤلفون: | Fargher HA; Department of Chemistry & Biochemistry, Materials Science Institute, and Knight Campus for Accelerating Scientific Impact, University of Oregon Eugene OR 97403-1253 USA haley@uoregon.edu pluth@uoregon.edu dwj@uoregon.edu., Nickels RA; Department of Chemistry & Biochemistry, Materials Science Institute, and Knight Campus for Accelerating Scientific Impact, University of Oregon Eugene OR 97403-1253 USA haley@uoregon.edu pluth@uoregon.edu dwj@uoregon.edu., de Faria TP; Department of Chemistry & Biochemistry, Materials Science Institute, and Knight Campus for Accelerating Scientific Impact, University of Oregon Eugene OR 97403-1253 USA haley@uoregon.edu pluth@uoregon.edu dwj@uoregon.edu., Haley MM; Department of Chemistry & Biochemistry, Materials Science Institute, and Knight Campus for Accelerating Scientific Impact, University of Oregon Eugene OR 97403-1253 USA haley@uoregon.edu pluth@uoregon.edu dwj@uoregon.edu., Pluth MD; Department of Chemistry & Biochemistry, Materials Science Institute, and Knight Campus for Accelerating Scientific Impact, University of Oregon Eugene OR 97403-1253 USA haley@uoregon.edu pluth@uoregon.edu dwj@uoregon.edu., Johnson DW; Department of Chemistry & Biochemistry, Materials Science Institute, and Knight Campus for Accelerating Scientific Impact, University of Oregon Eugene OR 97403-1253 USA haley@uoregon.edu pluth@uoregon.edu dwj@uoregon.edu. |
| المصدر: | RSC advances [RSC Adv] 2021 Aug 04; Vol. 11 (43), pp. 26581-26585. Date of Electronic Publication: 2021 Aug 04 (Print Publication: 2021). |
| نوع المنشور: | Journal Article |
| اللغة: | English |
| بيانات الدورية: | Publisher: Royal Society of Chemistry Country of Publication: England NLM ID: 101581657 Publication Model: eCollection Cited Medium: Internet ISSN: 2046-2069 (Electronic) Linking ISSN: 20462069 NLM ISO Abbreviation: RSC Adv Subsets: PubMed not MEDLINE |
| أسماء مطبوعة: | Original Publication: Cambridge [England] : Royal Society of Chemistry, [2011]- |
| مستخلص: | We highlight a convenient synthesis to selectively deuterate an aryl C-H hydrogen bond donor in an arylethynyl bisurea supramolecular anion receptor and use the Perrin method of competitive titrations to study the deuterium equilibrium isotope effects (DEIE) of anion binding for HS - , Cl - , and Br - . This work highlights the utility and also challenges in using this method to determine EIE with highly reactive and/or weakly binding anions. Competing Interests: There are no conflicts to declare. (This journal is © The Royal Society of Chemistry.) |
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| معلومات مُعتمدة: | R01 GM087398 United States GM NIGMS NIH HHS |
| تواريخ الأحداث: | Date Created: 20220428 Latest Revision: 20231212 |
| رمز التحديث: | 20231215 |
| مُعرف محوري في PubMed: | PMC9037421 |
| DOI: | 10.1039/d1ra05711a |
| PMID: | 35479978 |
| قاعدة البيانات: | MEDLINE |
Full Text Finder | تدمد: | 2046-2069 |
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| DOI: | 10.1039/d1ra05711a |