دورية أكاديمية
Out-of-equilibrium dynamics driven by photoinduced charge transfer in CsCoFe Prussian blue analogue nanocrystals.
| العنوان: | Out-of-equilibrium dynamics driven by photoinduced charge transfer in CsCoFe Prussian blue analogue nanocrystals. |
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| المؤلفون: | Zerdane S; Univ. Rennes, CNRS, IPR (Institut de Physique de Rennes) - UMR 6251, F-35000 Rennes, France. eric.collet@univ-rennes1.fr.; SwissFEL, Paul Scherrer Institut, Villigen, PSI, Switzerland. serhane.zerdane@psi.ch., Hervé M; Univ. Rennes, CNRS, IPR (Institut de Physique de Rennes) - UMR 6251, F-35000 Rennes, France. eric.collet@univ-rennes1.fr., Mazerat S; Institut de Chimie Moléculaire et des Matériaux d'Orsay, CNRS, Université Paris-Saclay, Orsay, France. talal.mallah@u-psud.fr., Catala L; Institut de Chimie Moléculaire et des Matériaux d'Orsay, CNRS, Université Paris-Saclay, Orsay, France. talal.mallah@u-psud.fr., Alonso-Mori R; Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, USA., Glownia JM; Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, USA., Song S; Linac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, USA., Levantino M; ESRF-The European Synchrotron, Grenoble, France. marco.cammarata@esrf.fr., Mallah T; Institut de Chimie Moléculaire et des Matériaux d'Orsay, CNRS, Université Paris-Saclay, Orsay, France. talal.mallah@u-psud.fr., Cammarata M; Univ. Rennes, CNRS, IPR (Institut de Physique de Rennes) - UMR 6251, F-35000 Rennes, France. eric.collet@univ-rennes1.fr.; ESRF-The European Synchrotron, Grenoble, France. marco.cammarata@esrf.fr., Collet E; Univ. Rennes, CNRS, IPR (Institut de Physique de Rennes) - UMR 6251, F-35000 Rennes, France. eric.collet@univ-rennes1.fr. |
| المصدر: | Faraday discussions [Faraday Discuss] 2022 Sep 15; Vol. 237 (0), pp. 224-236. Date of Electronic Publication: 2022 Sep 15. |
| نوع المنشور: | Journal Article |
| اللغة: | English |
| بيانات الدورية: | Publisher: Faraday Division, Royal Society of Chemistry Country of Publication: England NLM ID: 9212301 Publication Model: Electronic Cited Medium: Internet ISSN: 1364-5498 (Electronic) Linking ISSN: 13596640 NLM ISO Abbreviation: Faraday Discuss Subsets: PubMed not MEDLINE; MEDLINE |
| أسماء مطبوعة: | Original Publication: London : Faraday Division, Royal Society of Chemistry, c1992- |
| مستخلص: | In this paper we study the out-of-equilibrium dynamics associated with photoinduced charge-transfer (CT) in cyanide-bridged Co-Fe Prussian blue analogue nanocrystals. In these coordination networks, the structural trapping of the photoinduced CT polaron involves local electronic and structural reorganizations. Femtosecond X-ray and optical absorption spectroscopies show that the local structural trapping process occurs on similar timescale for particles with 11 nm and 70 nm sizes. The local photoinduced spin transition, elongating the Co-N bonds and driving the Co III Fe II → Co II Fe III CT, activates coherent lattice torsion modes. The elastic deformation waves, launched by these bond elongations, drive macroscopic volume expansion and breathing of the particles. The timescale of this macroscopic deformation depends strongly on the size of the particle, which is more evidence of the multiscale nature of photoinduced phenomena in molecular materials. |
| تواريخ الأحداث: | Date Created: 20220609 Latest Revision: 20220916 |
| رمز التحديث: | 20231215 |
| DOI: | 10.1039/d2fd00015f |
| PMID: | 35678517 |
| قاعدة البيانات: | MEDLINE |
| تدمد: | 1364-5498 |
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| DOI: | 10.1039/d2fd00015f |