دورية أكاديمية
A Greener Route to Blue: Solid-State Synthesis of Phthalocyanines.
| العنوان: | A Greener Route to Blue: Solid-State Synthesis of Phthalocyanines. |
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| المؤلفون: | Langerreiter D; Department of Bioproducts and Biosystems, Aalto University, 02150, Espoo, Finland., Kostiainen MA; Department of Bioproducts and Biosystems, Aalto University, 02150, Espoo, Finland., Kaabel S; Department of Bioproducts and Biosystems, Aalto University, 02150, Espoo, Finland., Anaya-Plaza E; Department of Bioproducts and Biosystems, Aalto University, 02150, Espoo, Finland. |
| المصدر: | Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2022 Oct 17; Vol. 61 (42), pp. e202209033. Date of Electronic Publication: 2022 Aug 16. |
| نوع المنشور: | Journal Article; Research Support, Non-U.S. Gov't |
| اللغة: | English |
| بيانات الدورية: | Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 0370543 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1521-3773 (Electronic) Linking ISSN: 14337851 NLM ISO Abbreviation: Angew Chem Int Ed Engl Subsets: MEDLINE |
| أسماء مطبوعة: | Publication: <2004-> : Weinheim : Wiley-VCH Original Publication: Weinheim/Bergstr. : New York, : Verlag Chemie ; Academic Press, c1962- |
| مواضيع طبية MeSH: | Caustics* , Deanol*, Coloring Agents ; Indoles ; Isoindoles ; Solvents ; Water |
| مستخلص: | Phthalocyanines are important organic dyes with a broad applicability in optoelectronics, catalysis, sensing and nanomedicine. Currently, phthalocyanines are synthetized in high boiling organic solvents, like dimethylaminoethanol (DMAE), which is a flammable, corrosive, and bioactive substance, miscible with water and harmful to the environment. Here we show a new solid-state approach for the high-yielding synthesis of phthalocyanines, which reduces up to 100-fold the amount of DMAE. Through systematic screening of solid-state reaction parameters, carried out by ball-milling and aging, we reveal the influence of key variables-temperature, presence of a template, and the amount and role of DMAE in the conversion of tBu phthalonitrile to tetra-tBu phthalocyanine. These results set the foundations to synthesize these high-performance dyes through a greener approach, opening the field of solid-state synthesis to a wider family of phthalocyanines. (© 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.) |
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| فهرسة مساهمة: | Keywords: Green Chemistry; Phthalocyanine; Solid-State Synthesis |
| المشرفين على المادة: | 0 (Caustics) 0 (Coloring Agents) 0 (Indoles) 0 (Isoindoles) 0 (Solvents) 059QF0KO0R (Water) 2N6K9DRA24 (Deanol) V5PUF4VLGY (phthalocyanine) |
| تواريخ الأحداث: | Date Created: 20220725 Date Completed: 20221012 Latest Revision: 20230107 |
| رمز التحديث: | 20230107 |
| مُعرف محوري في PubMed: | PMC9804881 |
| DOI: | 10.1002/anie.202209033 |
| PMID: | 35876617 |
| قاعدة البيانات: | MEDLINE |
Full Text Finder | تدمد: | 1521-3773 |
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| DOI: | 10.1002/anie.202209033 |