دورية أكاديمية

Dimensionality Mediated Highly Repeatable and Fast Transformation of Coordination Polymer Single Crystals for All-Optical Data Processing.

التفاصيل البيبلوغرافية
العنوان: Dimensionality Mediated Highly Repeatable and Fast Transformation of Coordination Polymer Single Crystals for All-Optical Data Processing.
المؤلفون: Kulachenkov N; School of Physics and Engineering, ITMO University, St. Petersburg 197101, Russia., Barsukova M; Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk 630090, Russia.; Functional Materials Design, Discovery and Development Research Group (FMD3), Advanced Membranes and Porous Materials Center (AMPM), Division of Physical Sciences and Engineering (PSE), King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia., Alekseevskiy P; School of Physics and Engineering, ITMO University, St. Petersburg 197101, Russia., Sapianik AA; Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk 630090, Russia.; Functional Materials Design, Discovery and Development Research Group (FMD3), Advanced Membranes and Porous Materials Center (AMPM), Division of Physical Sciences and Engineering (PSE), King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia., Sergeev M; School of Physics and Engineering, ITMO University, St. Petersburg 197101, Russia., Yankin A; School of Physics and Engineering, ITMO University, St. Petersburg 197101, Russia., Krasilin AA; School of Physics and Engineering, ITMO University, St. Petersburg 197101, Russia.; Ioffe Institute, St. Petersburg 194021, Russia., Bachinin S; School of Physics and Engineering, ITMO University, St. Petersburg 197101, Russia., Shipilovskikh S; School of Physics and Engineering, ITMO University, St. Petersburg 197101, Russia.; Department of Chemistry, Perm State University, Perm, 614990, Russia., Poturaev P; Department of Chemistry, Perm State University, Perm, 614990, Russia., Medvedeva N; Department of Chemistry, Perm State University, Perm, 614990, Russia., Denislamova E; Perm National Research Polytechnic University, Perm 614990, Russia., Zelenovskiy PS; Institute of Natural Sciences and Mathematics, Ural Federal University, Yekaterinburg 620000, Russia., Shilovskikh VV; St. Petersburg State University, St. Petersburg 198504, Russia., Kenzhebayeva Y; School of Physics and Engineering, ITMO University, St. Petersburg 197101, Russia., Efimova A; School of Physics and Engineering, ITMO University, St. Petersburg 197101, Russia., Novikov AS; Saint Petersburg State University, Saint Petersburg 198504, Russia.; Peoples' Friendship University of Russia (RUDN University), Moscow 117198, Russia., Lunev A; School of Physics and Engineering, ITMO University, St. Petersburg 197101, Russia., Fedin VP; Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk 630090, Russia., Milichko VA; School of Physics and Engineering, ITMO University, St. Petersburg 197101, Russia.; Institut Jean Lamour, Universit de Lorraine, UMR CNRS 7198, 54011 Nancy, France.
المصدر: Nano letters [Nano Lett] 2022 Sep 14; Vol. 22 (17), pp. 6972-6981. Date of Electronic Publication: 2022 Aug 26.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: American Chemical Society Country of Publication: United States NLM ID: 101088070 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1530-6992 (Electronic) Linking ISSN: 15306984 NLM ISO Abbreviation: Nano Lett Subsets: PubMed not MEDLINE; MEDLINE
أسماء مطبوعة: Original Publication: Washington, DC : American Chemical Society, c2001-
مستخلص: A family of coordination polymers (CPs) based on dynamic structural elements are of great fundamental and commercial interest addressing modern problems in controlled molecular separation, catalysis, and even data processing. Herein, the endurance and fast structural dynamics of such materials at ambient conditions are still a fundamental challenge. Here, we report on the design of a series of Cu-based CPs [Cu(bImB)Cl 2 ] and [Cu(bImB) 2 Cl 2 ] with flexible ligand bImB (1,4-bis(imidazol-1-yl)butane) packed into one- and two-dimensional (1D, 2D) structures demonstrating dimensionality mediated flexibility and reversible structural transformations. Using the laser pulses as a fast source of activation energy, we initiate CP heating followed by anisotropic thermal expansion and 0.2-0.8% volume changes with the record transformation rates from 2220 to 1640 s -1 for 1D and 2D CPs, respectively. The endurance over 10 3 cycles of structural transformations, achieved for the CPs at ambient conditions, allows demonstrating optical fiber integrated all-optical data processing.
فهرسة مساهمة: Keywords: Coordination polymers; data processing; flexibility; in situ spectroscopy; low-dimensional structures; structural transformation
تواريخ الأحداث: Date Created: 20220826 Latest Revision: 20220914
رمز التحديث: 20231215
DOI: 10.1021/acs.nanolett.2c01770
PMID: 36018814
قاعدة البيانات: MEDLINE
الوصف
تدمد:1530-6992
DOI:10.1021/acs.nanolett.2c01770