التفاصيل البيبلوغرافية
| العنوان: |
Periodic Trends within Actinyl(VI) Nitrates and Their Structures, Vibrational Spectra, and Electronic Properties. |
| المؤلفون: |
Autillo M; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States., Wilson RE; Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States., Vasiliu M; Department of Chemistry and Biochemistry, The University of Alabama, Tuscaloosa, Alabama 35487, United States., de Melo GF; Department of Chemistry and Biochemistry, The University of Alabama, Tuscaloosa, Alabama 35487, United States., Dixon DA; Department of Chemistry and Biochemistry, The University of Alabama, Tuscaloosa, Alabama 35487, United States. |
| المصدر: |
Inorganic chemistry [Inorg Chem] 2022 Oct 03; Vol. 61 (39), pp. 15607-15618. Date of Electronic Publication: 2022 Sep 21. |
| نوع المنشور: |
Journal Article |
| اللغة: |
English |
| بيانات الدورية: |
Publisher: American Chemical Society Country of Publication: United States NLM ID: 0366543 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1520-510X (Electronic) Linking ISSN: 00201669 NLM ISO Abbreviation: Inorg Chem Subsets: PubMed not MEDLINE; MEDLINE |
| أسماء مطبوعة: |
Original Publication: [Easton, Pa.] American Chemical Society. |
| مستخلص: |
A series of actinyl(VI) nitrate salts of the form MAnO 2 (NO 3 ) 3 , where M = NH 4 + K + , Rb + , Cs + , and Me 4 N + and AnO 2 2+ = U, Np, Pu, and AnO 2 (NO 3 ) 2 (H 2 O) 2 ·H 2 O, and the uranyl tetranitrates M 2 UO 2 (NO 3 ) 4 have been synthesized from aqueous solution and their structures determined using single-crystal X-ray diffraction. Together, these complexes represent an isostructural series of actinide complexes among the salts crystallized with the same charge-compensating cation and have been studied using vibrational spectroscopy including Raman and Fourier-transform infrared. Periodic trends in both the structural properties of these complexes and their vibrational spectra are presented and discussed, in particular the invariant nature of the O≡An≡O asymmetric stretching frequencies observed across the actinyl series. Electronic structure calculations were performed at a variety of levels of theory to aid in the interpretation of the vibrational data and to correlate trends in the data with the underlying electronic properties of these molecules. |
| تواريخ الأحداث: |
Date Created: 20220921 Latest Revision: 20221003 |
| رمز التحديث: |
20231215 |
| DOI: |
10.1021/acs.inorgchem.2c02434 |
| PMID: |
36130052 |
| قاعدة البيانات: |
MEDLINE |
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