دورية أكاديمية

The EDLC Energy Storage Device Based on a Natural Gelatin (NG) Biopolymer: Tuning the Capacitance through Plasticizer Variation.

التفاصيل البيبلوغرافية
العنوان: The EDLC Energy Storage Device Based on a Natural Gelatin (NG) Biopolymer: Tuning the Capacitance through Plasticizer Variation.
المؤلفون: Aziz SB; Hameed Majid Advanced Polymeric Materials Research Lab., Physics Department, College of Science, University of Sulaimani, Qlyasan Street, Kurdistan Regional Government, Sulaimani 46001, Iraq.; The Development Center for Research and Training (DCRT), University of Human Development, Kurdistan Region of Iraq, Sulaymaniyah 46001, Iraq., Dannoun EMA; Associate Chair of the Department of Mathematics and Science, Woman Campus, Prince Sultan University, P.O. Box 66833, Riyadh 11586, Saudi Arabia., Abdullah SN; Department of Chemistry, College of Science, University of Sulaimani, Qlyasan Street, Kurdistan Regional Government, Sulaimani 46001, Iraq., Ghareeb HO; Department of Chemistry, College of Science, University of Sulaimani, Qlyasan Street, Kurdistan Regional Government, Sulaimani 46001, Iraq., Abdullah RM; Hameed Majid Advanced Polymeric Materials Research Lab., Physics Department, College of Science, University of Sulaimani, Qlyasan Street, Kurdistan Regional Government, Sulaimani 46001, Iraq., Abdalrahman AA; Hameed Majid Advanced Polymeric Materials Research Lab., Physics Department, College of Science, University of Sulaimani, Qlyasan Street, Kurdistan Regional Government, Sulaimani 46001, Iraq., Nofal MM; Department of Mathematics and Science, Prince Sultan University, P.O. Box 66833, Riyadh 11586, Saudi Arabia., Kakroo S; Physics Department, Faculty of Science, Jazan University, P.O. Box 114, Jazan 45142, Saudi Arabia.
المصدر: Polymers [Polymers (Basel)] 2022 Nov 21; Vol. 14 (22). Date of Electronic Publication: 2022 Nov 21.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: MDPI Country of Publication: Switzerland NLM ID: 101545357 Publication Model: Electronic Cited Medium: Internet ISSN: 2073-4360 (Electronic) Linking ISSN: 20734360 NLM ISO Abbreviation: Polymers (Basel) Subsets: PubMed not MEDLINE
أسماء مطبوعة: Original Publication: Basel : MDPI
مستخلص: A solution casting method has been utilisedto fabricate plasticisednatural gelatin (NG)-based polymer electrolyte films. The NG electrolyte with 50 wt.% glycerol and 13 wt.% sodium nitrate (NaNO 3 ) attained the highest ionic conductivity of 1.67 × 10 -4 S cm -1 . Numerous techniques were used to characterisethe NG films to assess their electrochemical performance. The data obtained from impedance spectroscopy for the plasticisedsystem, such as bulk resistance (Rb), arerelatively low. Thiscomprehensive study has been focused on dielectric characteristics and electric modulus parameters. The plasticisedsystem has shown eligibility for practice in energy storage devices with electrochemical strength up to 2.85 V. The TNM data based on ion transference number (tion) and electron transference number (te) determine the identity of the main charge carrier, ion. The redox peaks in the cyclic voltammograms have not been observed as evidence of charge accumulation other than the Faradaic process at the electrode-electrolyte interface. The GCD plot reveals a triangle shape and records arelatively low drop voltage. The high average efficiency of 90% with low ESR has been achieved over 500 cycles, indicating compatibility between electrolyte and electrode. The average power density and energy density of the plasticisedare 700 W/kg and 8 Wh/kg, respectively.
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فهرسة مساهمة: Keywords: CV and GCD; EIS; LSV and TNM; NaNO3 salt; energy storage device; glycerol plasticizer; natural polymer
تواريخ الأحداث: Date Created: 20221126 Latest Revision: 20221213
رمز التحديث: 20231215
مُعرف محوري في PubMed: PMC9697460
DOI: 10.3390/polym14225044
PMID: 36433172
قاعدة البيانات: MEDLINE
الوصف
تدمد:2073-4360
DOI:10.3390/polym14225044