Thermally Stable Perovskite Solar Cells by All-Vacuum Deposition.

التفاصيل البيبلوغرافية
العنوان:	Thermally Stable Perovskite Solar Cells by All-Vacuum Deposition.
المؤلفون:	Yuan Q; Department of Physics, University of Oxford, Clarendon Laboratory, Parks Road, OxfordOX1 3PU, United Kingdom., Lohmann KB; Department of Physics, University of Oxford, Clarendon Laboratory, Parks Road, OxfordOX1 3PU, United Kingdom., Oliver RDJ; Department of Physics, University of Oxford, Clarendon Laboratory, Parks Road, OxfordOX1 3PU, United Kingdom., Ramadan AJ; Department of Physics, University of Oxford, Clarendon Laboratory, Parks Road, OxfordOX1 3PU, United Kingdom., Yan S; Department of Physics, University of Oxford, Clarendon Laboratory, Parks Road, OxfordOX1 3PU, United Kingdom., Ball JM; Department of Physics, University of Oxford, Clarendon Laboratory, Parks Road, OxfordOX1 3PU, United Kingdom., Christoforo MG; Department of Physics, University of Oxford, Clarendon Laboratory, Parks Road, OxfordOX1 3PU, United Kingdom., Noel NK; Department of Physics, University of Oxford, Clarendon Laboratory, Parks Road, OxfordOX1 3PU, United Kingdom., Snaith HJ; Department of Physics, University of Oxford, Clarendon Laboratory, Parks Road, OxfordOX1 3PU, United Kingdom., Herz LM; Department of Physics, University of Oxford, Clarendon Laboratory, Parks Road, OxfordOX1 3PU, United Kingdom.; Institute for Advanced Study, Technical University of Munich, Lichtenbergstrasse 2a, GarchingD-85748, Germany., Johnston MB; Department of Physics, University of Oxford, Clarendon Laboratory, Parks Road, OxfordOX1 3PU, United Kingdom.
المصدر:	ACS applied materials & interfaces [ACS Appl Mater Interfaces] 2023 Jan 11; Vol. 15 (1), pp. 772-781. Date of Electronic Publication: 2022 Dec 23.
نوع المنشور:	Journal Article
اللغة:	English
بيانات الدورية:	Publisher: American Chemical Society Country of Publication: United States NLM ID: 101504991 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1944-8252 (Electronic) Linking ISSN: 19448244 NLM ISO Abbreviation: ACS Appl Mater Interfaces Subsets: PubMed not MEDLINE; MEDLINE
أسماء مطبوعة:	Original Publication: Washington, D.C. : American Chemical Society
مستخلص:	Vacuum deposition is a solvent-free method suitable for growing thin films of metal halide perovskite (MHP) semiconductors. However, most reports of high-efficiency solar cells based on such vacuum-deposited MHP films incorporate solution-processed hole transport layers (HTLs), thereby complicating prospects of industrial upscaling and potentially affecting the overall device stability. In this work, we investigate organometallic copper phthalocyanine (CuPc) and zinc phthalocyanine (ZnPc) as alternative, low-cost, and durable HTLs in all-vacuum-deposited solvent-free formamidinium-cesium lead triodide [CH(NH 2 ) 2 ] 0.83 Cs 0.17 PbI 3 (FACsPbI 3 ) perovskite solar cells. We elucidate that the CuPc HTL, when employed in an "inverted" p-i-n solar cell configuration, attains a solar-to-electrical power conversion efficiency of up to 13.9%. Importantly, unencapsulated devices as large as 1 cm ² exhibited excellent long-term stability, demonstrating no observable degradation in efficiency after more than 5000 h in storage and 3700 h under 85 °C thermal stressing in N 2 atmosphere.
References:	ACS Energy Lett. 2020 Mar 13;5(3):710-717. (PMID: 32296733) Science. 2020 Dec 11;370(6522):1300-1309. (PMID: 33303611) Nature. 2013 Sep 19;501(7467):395-8. (PMID: 24025775) Science. 2016 Jan 8;351(6269):151-5. (PMID: 26744401) ACS Energy Lett. 2022 Jun 10;7(6):1903-1911. (PMID: 35719271) ACS Appl Mater Interfaces. 2019 Aug 14;11(32):28851-28857. (PMID: 31314481) ACS Energy Lett. 2020 Aug 14;5(8):2498-2504. (PMID: 32832697) ACS Nano. 2022 Jun 28;16(6):9640-9650. (PMID: 35609245) Sci Adv. 2022 Jul 15;8(28):eabo7422. (PMID: 35857518) Nature. 2021 Oct;598(7881):444-450. (PMID: 34671136) Nano Lett. 2014 Oct 8;14(10):5561-8. (PMID: 25226226) ACS Appl Mater Interfaces. 2020 Sep 2;12(35):39261-39272. (PMID: 32805961) Science. 2020 Jul 3;369(6499):96-102. (PMID: 32631893) Acc Chem Res. 2016 Jan 19;49(1):146-54. (PMID: 26653572) J Am Chem Soc. 2009 May 6;131(17):6050-1. (PMID: 19366264) ACS Energy Lett. 2021 Feb 12;6(2):827-836. (PMID: 34568574) J Am Chem Soc. 2022 Jun 1;144(21):9500-9509. (PMID: 35594143) Nanotechnology. 2020 Jan 31;31(6):065401. (PMID: 31627206) Sci Rep. 2021 Jul 27;11(1):15299. (PMID: 34315927) Nature. 2021 Feb;590(7847):587-593. (PMID: 33627807) Adv Mater. 2014 Mar 12;26(10):1584-9. (PMID: 24757716) J Phys Chem Lett. 2018 Mar 1;9(5):1041-1046. (PMID: 29432009) Nature. 2019 Mar;567(7749):511-515. (PMID: 30918371) RSC Adv. 2018 Aug 23;8(52):29899-29908. (PMID: 35547320) Science. 2016 Nov 18;354(6314):861-865. (PMID: 27856902)
فهرسة مساهمة:	Keywords: hole transport layer; metal halide perovskite; solar cell; thermal stability; vapor deposition
تواريخ الأحداث:	Date Created: 20221223 Date Completed: 20230112 Latest Revision: 20230116
رمز التحديث:	20230116
مُعرف محوري في PubMed:	PMC9837819
DOI:	10.1021/acsami.2c14658
PMID:	36563084
قاعدة البيانات:	MEDLINE

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الوصف
تدمد:	1944-8252
DOI:	10.1021/acsami.2c14658