دورية أكاديمية
أعرض في EDS

Functionalized β-Cyclodextrins Catalyzed Environment-Friendly Cycloaddition of Carbon Dioxide and Epoxides.

التفاصيل البيبلوغرافية
العنوان: Functionalized β-Cyclodextrins Catalyzed Environment-Friendly Cycloaddition of Carbon Dioxide and Epoxides.
المؤلفون: Wen Q; College of Chemistry and Materials Science, South-Central Minzu University, Wuhan 430074, China., Yuan X; College of Chemistry and Materials Science, South-Central Minzu University, Wuhan 430074, China., Zhou Q; College of Chemistry and Materials Science, South-Central Minzu University, Wuhan 430074, China., Yang HJ; College of Chemistry and Materials Science, South-Central Minzu University, Wuhan 430074, China., Jiang Q; College of Chemistry and Materials Science, South-Central Minzu University, Wuhan 430074, China., Hu J; College of Chemistry and Materials Science, South-Central Minzu University, Wuhan 430074, China., Guo CY; School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 100049, China.
المصدر: Materials (Basel, Switzerland) [Materials (Basel)] 2022 Dec 21; Vol. 16 (1). Date of Electronic Publication: 2022 Dec 21.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: MDPI Country of Publication: Switzerland NLM ID: 101555929 Publication Model: Electronic Cited Medium: Print ISSN: 1996-1944 (Print) Linking ISSN: 19961944 NLM ISO Abbreviation: Materials (Basel) Subsets: PubMed not MEDLINE
أسماء مطبوعة: Publication: May 2010- : Basel, Switzerland : MDPI
Original Publication: Basel, Switzerland : Molecular Diversity Preservation International, 2008-2010.
مستخلص: Ammonium, imidazole, or pyridinium functionalized β-cyclodextrins (β-CDs) were used as efficient one-component bifunctional catalysts for the coupling reaction of carbon dioxide (CO 2 ) and epoxide without the addition of solvent and metal. The influence of different catalysts and reaction parameters on the catalytic performance were examined in detail. Under optimal conditions, Im-CD1-I catalysts functionalized with imidazole groups were able to convert various epoxides into target products with high selectivity and good conversion rates. The one-component bifunctional catalysts can also be recovered easily by filtration and reused at least for five times with only slight decrease in catalytic performance. Finally, a possible process for hydroxyl group-assisted ring-opening of epoxide and functionalized group- induced activation of CO 2 was presented.
References: Dalton Trans. 2017 Oct 17;46(40):13783-13792. (PMID: 28959801)
ChemSusChem. 2015 Aug 10;8(15):2436-54. (PMID: 26119776)
Phys Chem Chem Phys. 2012 Aug 21;14(31):11021-6. (PMID: 22710728)
J Org Chem. 2021 Feb 19;86(4):3422-3432. (PMID: 33512164)
Dalton Trans. 2015 Feb 21;44(7):3356-66. (PMID: 25599815)
Chemistry. 2016 Jan 4;22(1):79-82. (PMID: 26482439)
Top Curr Chem (Cham). 2017 Jun;375(3):50. (PMID: 28439724)
Dalton Trans. 2013 May 21;42(19):6732-5. (PMID: 23584495)
J Am Chem Soc. 2014 Oct 29;136(43):15270-9. (PMID: 25268908)
Angew Chem Int Ed Engl. 2020 Dec 14;59(51):23291-23298. (PMID: 32869449)
Chem Commun (Camb). 2017 Nov 30;53(96):12970-12973. (PMID: 29160877)
ACS Appl Mater Interfaces. 2016 May 25;8(20):12812-21. (PMID: 27142654)
J Nanosci Nanotechnol. 2019 Jun 1;19(6):3263-3268. (PMID: 30744752)
Carbohydr Polym. 2017 Nov 1;175:575-583. (PMID: 28917903)
Dalton Trans. 2017 Dec 21;46(47):16426-16431. (PMID: 29119189)
Angew Chem Int Ed Engl. 2015 Jan 2;54(1):134-8. (PMID: 25370986)
ACS Appl Mater Interfaces. 2022 Apr 27;14(16):18589-18599. (PMID: 35417126)
Chem Commun (Camb). 2011 Feb 21;47(7):2131-3. (PMID: 21184008)
ACS Omega. 2020 Jul 13;5(29):18064-18072. (PMID: 32743180)
ChemSusChem. 2019 Aug 8;12(15):3410-3430. (PMID: 31099968)
Angew Chem Int Ed Engl. 2007;46(38):7255-8. (PMID: 17634988)
Dalton Trans. 2017 Nov 14;46(44):15399-15406. (PMID: 29077111)
Chem Commun (Camb). 2015 Aug 4;51(60):12076-9. (PMID: 26121326)
Chem Commun (Camb). 2018 Jan 4;54(4):342-345. (PMID: 29182177)
معلومات مُعتمدة: 51073175 National Natural Science Foundation of China
فهرسة مساهمة: Keywords: carbon dioxide fixation; cyclic carbonate; environment-friendliness; functionalized β-cyclodextrins; solvent- and metal-free catalysis
تواريخ الأحداث: Date Created: 20230108 Latest Revision: 20230111
رمز التحديث: 20240628
مُعرف محوري في PubMed: PMC9821656
DOI: 10.3390/ma16010053
PMID: 36614390
قاعدة البيانات: MEDLINE
الوصف
تدمد:1996-1944
DOI:10.3390/ma16010053