دورية أكاديمية
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Effects of Substituents on the Photophysical/Photobiological Properties of Mono-Substituted Corroles.

التفاصيل البيبلوغرافية
العنوان: Effects of Substituents on the Photophysical/Photobiological Properties of Mono-Substituted Corroles.
المؤلفون: de Souza VB; Bioinorganic and Porphyrinoids Materials Laboratory, Department of Chemistry, Federal University of Santa Maria, Santa Maria 97105-900, RS, Brazil., da Rocha VN; Department of Physics, Federal University of Santa Maria, Santa Maria 97105-900, RS, Brazil., Piquini PC; Department of Physics, Federal University of Santa Maria, Santa Maria 97105-900, RS, Brazil., Chaves OA; CQC-IMS, Department of Chemistry, University of Coimbra, Rua Larga, 3004-535 Coimbra, Portugal., Iglesias BA; Bioinorganic and Porphyrinoids Materials Laboratory, Department of Chemistry, Federal University of Santa Maria, Santa Maria 97105-900, RS, Brazil.
المصدر: Molecules (Basel, Switzerland) [Molecules] 2023 Feb 01; Vol. 28 (3). Date of Electronic Publication: 2023 Feb 01.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: MDPI Country of Publication: Switzerland NLM ID: 100964009 Publication Model: Electronic Cited Medium: Internet ISSN: 1420-3049 (Electronic) Linking ISSN: 14203049 NLM ISO Abbreviation: Molecules Subsets: MEDLINE
أسماء مطبوعة: Original Publication: Basel, Switzerland : MDPI, c1995-
مواضيع طبية MeSH: Porphyrins*/chemistry , Photochemotherapy*, Molecular Docking Simulation ; Photobiology
مستخلص: The trans -A 2 B-corrole series was prepared starting with 5-(pentafluorophenyl)dipyrromethene, which was then reacted with respective aryl-substituted aldehyde by Gryko synthesis. It was further characterized by HRMS and electrochemical methods. In addition, we investigated experimental photophysical properties (absorption, emission by steady-state and time-resolved fluorescence) in several solvents and TDDFT calculations, aggregation, photostability and reactive oxygen species generation (ROS), which are relevant when selecting photosensitizers used in photodynamic therapy and many other photo-applications. In addition, we also evaluated the biomolecule-binding properties with CT-DNA and HSA by spectroscopy, viscometry and molecular docking calculations assays.
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معلومات مُعتمدة: 403210/2021-6 National Council for Scientific and Technological Development; 305458/2021-3 National Council for Scientific and Technological Development; Financial code 001 Coordenação de Aperfeicoamento de Pessoal de Nível Superior; 21/2551-0002114-4 Fundação de Amparo à Pesquisa do Estado do Rio Grande do Sul
فهرسة مساهمة: Keywords: corroles; photobiology; photophysics; trans-A2B-corroles
المشرفين على المادة: 0 (corrole)
0 (Porphyrins)
تواريخ الأحداث: Date Created: 20230211 Date Completed: 20230214 Latest Revision: 20230214
رمز التحديث: 20230214
مُعرف محوري في PubMed: PMC9921392
DOI: 10.3390/molecules28031385
PMID: 36771053
قاعدة البيانات: MEDLINE
الوصف
تدمد:1420-3049
DOI:10.3390/molecules28031385