دورية أكاديمية
Pore Aperture Control Toward Size-Exclusion-Based Hydrocarbon Separations.
العنوان: | Pore Aperture Control Toward Size-Exclusion-Based Hydrocarbon Separations. |
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المؤلفون: | Lal B; Department of Chemistry, Northwestern University, 60208, Evanston, IL, USA.; Institute of Chemistry, Shah Abdul Latif University, 66020, Khairpur, Sindh, Pakistan., Idrees KB; Department of Chemistry, Northwestern University, 60208, Evanston, IL, USA., Xie H; Department of Chemistry, Northwestern University, 60208, Evanston, IL, USA., Smoljan CS; Department of Chemical and Biological Engineering, Northwestern University, 60208, Evanston, IL, USA., Shafaie S; Integrated Molecular Structure and Education Center, Northwestern University, 60208, Evanston, IL, USA., Islamoglu T; Department of Chemistry, Northwestern University, 60208, Evanston, IL, USA., Farha OK; Department of Chemistry, Northwestern University, 60208, Evanston, IL, USA.; Department of Chemical and Biological Engineering, Northwestern University, 60208, Evanston, IL, USA. |
المصدر: | Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2023 Apr 11; Vol. 62 (16), pp. e202219053. Date of Electronic Publication: 2023 Mar 06. |
نوع المنشور: | Journal Article |
اللغة: | English |
بيانات الدورية: | Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 0370543 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1521-3773 (Electronic) Linking ISSN: 14337851 NLM ISO Abbreviation: Angew Chem Int Ed Engl Subsets: PubMed not MEDLINE; MEDLINE |
أسماء مطبوعة: | Publication: <2004-> : Weinheim : Wiley-VCH Original Publication: Weinheim/Bergstr. : New York, : Verlag Chemie ; Academic Press, c1962- |
مستخلص: | Metal-organic frameworks (MOFs) have been proposed as a promising material for non-thermal chemical separations owing to their high structural diversity and tunability. Here, we report the synthesis of a zinc-based MOF containing a three-dimensional (3D) linker, bicyclo[2.2.2]octane-1,4-dicarboxylic acid, with high thermal stability towards the separation of hexane isomers. The incorporation of the 3D linker enhances the structural stability and provides well-defined pore apertures/channels with sub-Ångstrom precision. This precision allowed for the separation of similarly sized hexane isomers based on subtle differences in their kinetic diameters. Multi-component liquid phase batch experiments confirmed the separation of hexanes mixture into linear, monobranched, and dibranched isomers. This work represents a significant milestone in the construction of stable Zn-based MOFs and the incorporation of 3D linkers as a potential solution to challenging separations. (© 2023 Wiley-VCH GmbH.) |
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معلومات مُعتمدة: | DE-FG02-08ER15967 Office of Science |
فهرسة مساهمة: | Keywords: Hexanes; Metal-Organic Frameworks; Separation; Zn-MOF |
تواريخ الأحداث: | Date Created: 20230215 Date Completed: 20230403 Latest Revision: 20230403 |
رمز التحديث: | 20240628 |
DOI: | 10.1002/anie.202219053 |
PMID: | 36790793 |
قاعدة البيانات: | MEDLINE |
تدمد: | 1521-3773 |
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DOI: | 10.1002/anie.202219053 |