دورية أكاديمية
Highly dispersed Rh single atoms over graphitic carbon nitride as a robust catalyst for the hydroformylation reaction.
العنوان: | Highly dispersed Rh single atoms over graphitic carbon nitride as a robust catalyst for the hydroformylation reaction. |
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المؤلفون: | Jurado L; CNRS, LCC (Laboratoire de Chimie de Coordination), UPS, INPT, Université de Toulouse 205 Route de Narbonne F-31077 Toulouse Cedex 4 France rosa.axet@lcc-toulouse.fr., Esvan J; CIRIMAT, CNRS-INPT-UPS, Université de Toulouse 4 Allée Emile Monso 31030 Toulouse France., Luque-Álvarez LA; Departamento de Química Inorgánica e Instituto de Ciencia de Materiales de Sevilla, Centro Mixto CSIC-Universidad de Sevilla Av. Américo Vespucio 49 41092 Sevilla Spain., Bobadilla LF; Departamento de Química Inorgánica e Instituto de Ciencia de Materiales de Sevilla, Centro Mixto CSIC-Universidad de Sevilla Av. Américo Vespucio 49 41092 Sevilla Spain., Odriozola JA; Departamento de Química Inorgánica e Instituto de Ciencia de Materiales de Sevilla, Centro Mixto CSIC-Universidad de Sevilla Av. Américo Vespucio 49 41092 Sevilla Spain., Posada-Pérez S; Institut de Química Computacional i Catàlisi and Departament de Química, Universitat de Girona c/ Maria Aurèlia Capmany 69 17003 Girona Catalonia Spain., Poater A; Institut de Química Computacional i Catàlisi and Departament de Química, Universitat de Girona c/ Maria Aurèlia Capmany 69 17003 Girona Catalonia Spain., Comas-Vives A; Institute of Materials Chemistry, TU Wien 1060 Vienna Austria.; Departament de Química, Universitat Autònoma de Barcelona 08193 Cerdanyola del Vallès Catalonia Spain., Axet MR; CNRS, LCC (Laboratoire de Chimie de Coordination), UPS, INPT, Université de Toulouse 205 Route de Narbonne F-31077 Toulouse Cedex 4 France rosa.axet@lcc-toulouse.fr. |
المصدر: | Catalysis science & technology [Catal Sci Technol] 2023 Jan 12; Vol. 13 (5), pp. 1425-1436. Date of Electronic Publication: 2023 Jan 12 (Print Publication: 2023). |
نوع المنشور: | Journal Article |
اللغة: | English |
بيانات الدورية: | Publisher: Royal Society of Chemistry Country of Publication: England NLM ID: 101636664 Publication Model: eCollection Cited Medium: Print ISSN: 2044-4753 (Print) Linking ISSN: 20444753 NLM ISO Abbreviation: Catal Sci Technol Subsets: PubMed not MEDLINE |
أسماء مطبوعة: | Original Publication: Cambridge : Royal Society of Chemistry, 2011- |
مستخلص: | Rhodium-catalysed hydroformylation, effective tool in bulk and fine-chemical synthesis, predominantly uses soluble metal complexes. For that reason, the metal leaching and the catalyst recycling are still the major drawbacks of this process. Single-atom catalysts have emerged as a powerful tool to combine the advantages of both homogeneous and heterogeneous catalysts. Since using an appropriate support material is key to create stable, finely dispersed, single-atom catalysts, here we show that Rh atoms anchored on graphitic carbon nitride are robust catalysts for the hydroformylation reaction of styrene. Competing Interests: There are no conflicts to declare. (This journal is © The Royal Society of Chemistry.) |
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تواريخ الأحداث: | Date Created: 20230310 Latest Revision: 20230311 |
رمز التحديث: | 20230311 |
مُعرف محوري في PubMed: | PMC9986719 |
DOI: | 10.1039/d2cy02094g |
PMID: | 36895514 |
قاعدة البيانات: | MEDLINE |
تدمد: | 2044-4753 |
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DOI: | 10.1039/d2cy02094g |