دورية أكاديمية
Highly dispersed Rh single atoms over graphitic carbon nitride as a robust catalyst for the hydroformylation reaction.
| العنوان: | Highly dispersed Rh single atoms over graphitic carbon nitride as a robust catalyst for the hydroformylation reaction. |
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| المؤلفون: | Jurado L; CNRS, LCC (Laboratoire de Chimie de Coordination), UPS, INPT, Université de Toulouse 205 Route de Narbonne F-31077 Toulouse Cedex 4 France rosa.axet@lcc-toulouse.fr., Esvan J; CIRIMAT, CNRS-INPT-UPS, Université de Toulouse 4 Allée Emile Monso 31030 Toulouse France., Luque-Álvarez LA; Departamento de Química Inorgánica e Instituto de Ciencia de Materiales de Sevilla, Centro Mixto CSIC-Universidad de Sevilla Av. Américo Vespucio 49 41092 Sevilla Spain., Bobadilla LF; Departamento de Química Inorgánica e Instituto de Ciencia de Materiales de Sevilla, Centro Mixto CSIC-Universidad de Sevilla Av. Américo Vespucio 49 41092 Sevilla Spain., Odriozola JA; Departamento de Química Inorgánica e Instituto de Ciencia de Materiales de Sevilla, Centro Mixto CSIC-Universidad de Sevilla Av. Américo Vespucio 49 41092 Sevilla Spain., Posada-Pérez S; Institut de Química Computacional i Catàlisi and Departament de Química, Universitat de Girona c/ Maria Aurèlia Capmany 69 17003 Girona Catalonia Spain., Poater A; Institut de Química Computacional i Catàlisi and Departament de Química, Universitat de Girona c/ Maria Aurèlia Capmany 69 17003 Girona Catalonia Spain., Comas-Vives A; Institute of Materials Chemistry, TU Wien 1060 Vienna Austria.; Departament de Química, Universitat Autònoma de Barcelona 08193 Cerdanyola del Vallès Catalonia Spain., Axet MR; CNRS, LCC (Laboratoire de Chimie de Coordination), UPS, INPT, Université de Toulouse 205 Route de Narbonne F-31077 Toulouse Cedex 4 France rosa.axet@lcc-toulouse.fr. |
| المصدر: | Catalysis science & technology [Catal Sci Technol] 2023 Jan 12; Vol. 13 (5), pp. 1425-1436. Date of Electronic Publication: 2023 Jan 12 (Print Publication: 2023). |
| نوع المنشور: | Journal Article |
| اللغة: | English |
| بيانات الدورية: | Publisher: Royal Society of Chemistry Country of Publication: England NLM ID: 101636664 Publication Model: eCollection Cited Medium: Print ISSN: 2044-4753 (Print) Linking ISSN: 20444753 NLM ISO Abbreviation: Catal Sci Technol Subsets: PubMed not MEDLINE |
| أسماء مطبوعة: | Original Publication: Cambridge : Royal Society of Chemistry, 2011- |
| مستخلص: | Rhodium-catalysed hydroformylation, effective tool in bulk and fine-chemical synthesis, predominantly uses soluble metal complexes. For that reason, the metal leaching and the catalyst recycling are still the major drawbacks of this process. Single-atom catalysts have emerged as a powerful tool to combine the advantages of both homogeneous and heterogeneous catalysts. Since using an appropriate support material is key to create stable, finely dispersed, single-atom catalysts, here we show that Rh atoms anchored on graphitic carbon nitride are robust catalysts for the hydroformylation reaction of styrene. Competing Interests: There are no conflicts to declare. (This journal is © The Royal Society of Chemistry.) |
| References: | J Am Chem Soc. 2017 Dec 6;139(48):17694-17699. (PMID: 29125746) Phys Chem Chem Phys. 2017 Jun 21;19(24):15613-15638. (PMID: 28594419) Chem Soc Rev. 2020 Nov 21;49(22):8156-8178. (PMID: 32870221) Nat Commun. 2019 Oct 3;10(1):4488. (PMID: 31582746) Angew Chem Int Ed Engl. 2016 Dec 23;55(52):16054-16058. (PMID: 27862789) Chem Rev. 2020 Jan 22;120(2):734-813. (PMID: 31613601) Nat Commun. 2021 Aug 4;12(1):4698. (PMID: 34349125) Angew Chem Int Ed Engl. 2018 Nov 19;57(47):15316-15329. (PMID: 30080958) ChemSusChem. 2020 Oct 7;13(19):5231-5238. (PMID: 32687261) J Org Chem. 2022 Mar 4;87(5):2873-2886. (PMID: 35076236) Nat Nanotechnol. 2018 Aug;13(8):702-707. (PMID: 29941887) Angew Chem Int Ed Engl. 2015 Sep 14;54(38):11265-9. (PMID: 26230282) Chem Rev. 2020 Jan 22;120(2):623-682. (PMID: 31868347) Adv Mater. 2015 Nov 18;27(43):6906-13. (PMID: 26422111) Nat Commun. 2016 Dec 22;7:14036. (PMID: 28004661) Chemistry. 2022 Sep 22;28(53):e202200374. (PMID: 35768335) Chem Rev. 2020 Jan 22;120(2):1085-1145. (PMID: 31898888) Angew Chem Int Ed Engl. 2020 May 4;59(19):7430-7434. (PMID: 32037716) J Am Chem Soc. 2010 May 12;132(18):6294-5. (PMID: 20397632) J Am Chem Soc. 2020 Mar 18;142(11):5087-5096. (PMID: 32141745) Chem Rev. 2018 May 23;118(10):4981-5079. (PMID: 29658707) Nat Mater. 2009 Jan;8(1):76-80. (PMID: 18997776) |
| تواريخ الأحداث: | Date Created: 20230310 Latest Revision: 20230311 |
| رمز التحديث: | 20230311 |
| مُعرف محوري في PubMed: | PMC9986719 |
| DOI: | 10.1039/d2cy02094g |
| PMID: | 36895514 |
| قاعدة البيانات: | MEDLINE |
| تدمد: | 2044-4753 |
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| DOI: | 10.1039/d2cy02094g |