دورية أكاديمية
Improved analysis of folpet and captan in foods using liquid chromatography-triple quadrupole linear ion trap mass spectrometry: applying mass filtering, collision, and trapping conditions.
| العنوان: | Improved analysis of folpet and captan in foods using liquid chromatography-triple quadrupole linear ion trap mass spectrometry: applying mass filtering, collision, and trapping conditions. |
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| المؤلفون: | El-Sheikh AA; Agricultural Research Center, Central Laboratory of Residue Analysis of Pesticides and Heavy Metals in Foods, Dokki, P.O. Box 12311, Giza, Egypt.; Environment and Bio-Agriculture Department, Faculty of Agriculture, Al-Azhar University, P.O. Box 11884, Cairo, Egypt., Elhamalawy OH; Environment and Bio-Agriculture Department, Faculty of Agriculture, Al-Azhar University, P.O. Box 11884, Cairo, Egypt., Taha SM; Agricultural Research Center, Central Laboratory of Residue Analysis of Pesticides and Heavy Metals in Foods, Dokki, P.O. Box 12311, Giza, Egypt. sherif2taha@gmail.com., Eissa FI; Environment and Bio-Agriculture Department, Faculty of Agriculture, Al-Azhar University, P.O. Box 11884, Cairo, Egypt. |
| المصدر: | Analytical and bioanalytical chemistry [Anal Bioanal Chem] 2023 Jun; Vol. 415 (14), pp. 2693-2703. Date of Electronic Publication: 2023 Apr 11. |
| نوع المنشور: | Journal Article |
| اللغة: | English |
| بيانات الدورية: | Publisher: Springer-Verlag Country of Publication: Germany NLM ID: 101134327 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1618-2650 (Electronic) Linking ISSN: 16182642 NLM ISO Abbreviation: Anal Bioanal Chem Subsets: MEDLINE |
| أسماء مطبوعة: | Original Publication: Heidelberg : Springer-Verlag, 2002- |
| مواضيع طبية MeSH: | Captan* , Malus*/chemistry, Flour/analysis ; Reproducibility of Results ; Triticum ; Gas Chromatography-Mass Spectrometry/methods ; Chromatography, Liquid/methods ; Chromatography, High Pressure Liquid |
| مستخلص: | Accurate and highly sensitive analysis of folpet and captan was accomplished using liquid chromatography-triple quadrupole linear ion trap mass spectrometry (LC-QqQIT) with selective ion mode; mass filtering, collision, and trapping condition. Dimensional mass spectrometry (MS 3 ) parameters were optimized for the residue detection of folpet and captan in six food commodities (apples, tomatoes, sweet pepper, wheat flour, sesame seeds, and fennel seeds). The sample preparation method was based on the known QuEChERS protocol, except a mixture of acetonitrile/acetone was used for the sample extraction from the sesame seeds. The robustness and reliability of the developed MS 3 method were demonstrated by performing a full validation, according to SANTE/11312/2021, at 0.01-0.25 mg/kg. Recovery ranged from 83 to 118% with a relative standard deviation below 19% in all the tested commodities, and limits of quantifications (LOQs) were 0.01 mg/kg in apples and tomatoes; 0.03 mg/kg in sweet pepper; and 0.05 mg/kg in wheat flour, sesame seeds, and fennel seeds. Monitoring results showed that about 90% of apples contained captan residue, and in sweet pepper, concentrations of captan and folpet as high as 1.57 and 0.97 mg/kg were found, respectively. The novel developed MS 3 method enabled more reliable identification of these commonly problematic fungicides at lower LOQs than previously reported methods. (© 2023. Springer-Verlag GmbH Germany, part of Springer Nature.) |
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| فهرسة مساهمة: | Keywords: Captan; Folpet; LC-QqQIT; Linear ion trap; MS3; QuEChERS |
| المشرفين على المادة: | EOL5G26Q9F (Captan) X5NFK36917 (folpet) |
| تواريخ الأحداث: | Date Created: 20230410 Date Completed: 20230517 Latest Revision: 20230517 |
| رمز التحديث: | 20240628 |
| DOI: | 10.1007/s00216-023-04667-x |
| PMID: | 37037911 |
| قاعدة البيانات: | MEDLINE |
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Full Text Finder | تدمد: | 1618-2650 |
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| DOI: | 10.1007/s00216-023-04667-x |