دورية أكاديمية
Expedient Synthesis and Ring-Opening Metathesis Polymerization of Pyridinonorbornenes.
العنوان: | Expedient Synthesis and Ring-Opening Metathesis Polymerization of Pyridinonorbornenes. |
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المؤلفون: | Hancock SN; Department of Chemistry, Texas A&M University, College Station, Texas 77843, USA., Yuntawattana N; Department of Chemistry, Texas A&M University, College Station, Texas 77843, USA.; Present Address: Department of Materials Science, Faculty of Science, Kasetsart University, Bangkok, Thailand., Valdez SM; Department of Chemistry, Texas A&M University, College Station, Texas 77843, USA., Michaudel Q; Department of Chemistry, Texas A&M University, College Station, Texas 77843, USA.; Department of Materials Science and Engineering, Texas A&M University, College Station, Texas 77843, USA. |
المصدر: | Polymer chemistry [Polym Chem] 2022 Oct 21; Vol. 13 (39), pp. 5530-5535. Date of Electronic Publication: 2022 Sep 02. |
نوع المنشور: | Journal Article |
اللغة: | English |
بيانات الدورية: | Publisher: Royal Society of Chemistry Country of Publication: England NLM ID: 101562526 Publication Model: Print-Electronic Cited Medium: Print ISSN: 1759-9954 (Print) Linking ISSN: 17599954 NLM ISO Abbreviation: Polym Chem Subsets: PubMed not MEDLINE |
أسماء مطبوعة: | Original Publication: Cambridge, England : Royal Society of Chemistry |
مستخلص: | Pyridine-containing polymers are promising materials for a variety of applications from the capture of contaminants to the self-assembly of block copolymers. However, the innate Lewis basicity of the pyridine motif often hampers living polymerization catalyzed by transition-metal complexes. Herein, we report the expedient synthesis of pyridinonorbornene monomers via a [4+2] cycloaddition between 2,3-pyridynes and cyclopentadiene. Well-controlled ring-opening metathesis polymerization was enabled by careful structural design of the monomer. Polypyridinonorbornenes exhibited high T Competing Interests: Conflicts of interest There are no conflicts to declare. |
معلومات مُعتمدة: | R35 GM138079 United States GM NIGMS NIH HHS |
تواريخ الأحداث: | Date Created: 20230516 Latest Revision: 20231022 |
رمز التحديث: | 20231215 |
مُعرف محوري في PubMed: | PMC10168028 |
DOI: | 10.1039/d2py00857b |
PMID: | 37193226 |
قاعدة البيانات: | MEDLINE |
تدمد: | 1759-9954 |
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DOI: | 10.1039/d2py00857b |